61327-31-9Relevant articles and documents
Asymmetric Br?nsted Acid Catalyzed Substitution of Diaryl Methanols with Thiols and Alcohols for the Synthesis of Chiral Thioethers and Ethers
Chatupheeraphat, Adisak,Liao, Hsuan-Hung,Mader, Steffen,Sako, Makoto,Sasai, Hiroaki,Atodiresei, Iuliana,Rueping, Magnus
supporting information, p. 4803 - 4807 (2016/04/19)
An enantioselective addition of thiols and alcohols to aza-ortho-quinone methides, starting from diaryl methanols, was developed. The asymmetric additions occur under mild reaction conditions in the presence of chiral phosphoric acids and furnish the corresponding adducts with excellent yields and enantioselectivities. Take two: An enantioselective addition of thiols and alcohols to aza-ortho-quinone methides, starting from diaryl methanols, has been developed. The asymmetric oxa- and sulfa-Michael additions proceed under mild reaction conditions in the presence of chiral phosphoric acids to furnish the corresponding adducts with excellent yields and enantioselectivities.
Aminohaloborane in Organic Synthesis. X. A Convenient, Economical Exclusive ortho Substitution Reaction of N-Alkyl and N-Aminoalkyl Anilines
Sasakura, Kazuyuki,Terui, Yoshihiro,Sugasawa, Tsutomu
, p. 1836 - 1842 (2007/10/02)
A method for in situ generation of boron trichloride from boron trifluoride etherate and silicon tetrachloride in the presence of triethylamine, traced by boron-11 nuclear magnetic resonance (11B-NMR) spectroscopy, was successfully developed, thus elimina