6134-56-1

Basic information

• Product Name: 2-bromotetralin
• Synonyms: 2-bromotetralin;6-Bromotetralin
• CAS NO: 6134-56-1
• Molecular Formula: C₁₀H₁₁Br
• Molecular Weight: 211.1
• Mol File: 6134-56-1.mol
• Article Data: 12

Chemical Properties

• Boiling Point: 260.9°C at 760 mmHg
• Flash Point: 113°C
• Appearance: /
• Density: 1.384g/cm³
• Vapor Pressure: 0.0193mmHg at 25°C
• Refractive Index: 1.579
• Storage Temp.: Sealed in dry,Room Temperature
• CAS DataBase Reference: 2-bromotetralin(CAS DataBase Reference)
• NIST Chemistry Reference: 2-bromotetralin(6134-56-1)
• EPA Substance Registry System: 2-bromotetralin(6134-56-1)

Safety Data

• Hazardous Substances Data: 6134-56-1(Hazardous Substances Data)

Usage

General Description

2-Bromotetralin is a chemical compound with the formula C10H9Br. It is a brominated derivative of tetralin, a bicyclic aromatic hydrocarbon. 2-Bromotetralin is primarily used in the synthesis of various organic compounds and pharmaceuticals due to its ability to act as a building block for more complex molecules. It is also utilized as a research tool in chemical and pharmaceutical R&D. 2-Bromotetralin is known for its structural rigidity, aromaticity, and stability, making it a valuable intermediate in the production of fine chemicals and drug substances. It is also important in the development of new synthetic strategies for organic chemistry. Additionally, 2-Bromotetralin may have potential applications in drug discovery and development as well as in medicinal chemistry. Due to its high chemical reactivity and unique structure, 2-Bromotetralin has garnered significant attention in both academic and industrial research.

InChI:InChI=1/C10H11Br/c11-10-6-5-8-3-1-2-4-9(8)7-10/h5-7H,1-4H2

Upstream product

• 2217-43-8 6-amino-1,2,3,4-tetrahydronaphthalene 
• 119-64-2 tetralin 
• 5350-41-4 trimethylbenzylammonium bromide 
• 32281-97-3 7-bromo-3,4-dihydro-2H-naphthalen-1-one 
• 35656-89-4 4-(4-bromophenyl)butanoic acid 
• 108-86-1 bromobenzene 
• 6340-79-0 4-oxo-4-(4-bromophenyl)butanoic acid 

Downstream Products

• 6968-28-1 4-bromophthalic acid 
• 4242-18-6 5,6,7,8-tetrahydro-1-naphthalenecarboxylic acid 
• 1131-63-1 1,2,3,4-tetrahydro-2-naphthoic acid 
• 17104-67-5 6-cyano-1,2,3,4-tetrahydronaphthalene 
• 29809-13-0 5,6,7,8-tetrahydronaphthalene-1-carbonitrile 
• 405888-56-4 (5,6,7,8-tetrahydronaphthalen-2-yl)boronic acid 
• 1181381-85-0 4-[5,6,7,8-tetrahydro-naphthalen-2-yl]phenol 
• 580-13-2 2-bromonaphthalene 
• 627526-54-9 4,4,5,5-tetramethyl-2-(5,6,7,8-tetrahydronaphthalen-2-yl)-1,3,2-dioxaborolane 

Relevant articles and documents

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Visible-light-induced oxidation/[3 + 2] cycloaddition/oxidative aromatization to construct benzo[ a]carbazoles from 1,2,3,4-tetrahydronaphthalene and arylhydrazine hydrochlorides

An efficient synthesis of benzo[a]carbazoles via visible-light-induced tandem oxidation/[3 + 2] cycloaddition/oxidative aromatization reactions was reported. The benzylic C(sp3)-H of tetrahydronaphthalene was activated through visible-light photoredox catalyst with oxygen as the clean oxidant under mild reaction conditions. This protocol proceeds efficiently with broad substrate scope, and the mechanism study was performed.

Acceptorless Dehydrogenation of Hydrocarbons by Noble-Metal-Free Hybrid Catalyst System

A hybrid catalysis that comprises an acridinium photoredox catalyst, a thiophosphate organocatalyst, and a nickel catalyst-enabled acceptorless dehydrogenation of hydrocarbons is reported. The cationic nickel complex played a critical role in the reactivity. This is the first example of acceptorless dehydrogenation of hydrocarbons by base metal catalysis under mild reaction conditions of visible light irradiation at room temperature.