61539-89-7

Basic information

• Product Name: Benzene, (decylseleno)-
• CAS NO: 61539-89-7
• Molecular Formula: C16H26Se
• Molecular Weight: 297.342
• Mol File: 61539-89-7.mol
• Article Data: 12

Chemical Properties

• CAS DataBase Reference: Benzene, (decylseleno)-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzene, (decylseleno)-(61539-89-7)
• EPA Substance Registry System: Benzene, (decylseleno)-(61539-89-7)

Safety Data

• Hazardous Substances Data: 61539-89-7(Hazardous Substances Data)

Upstream product

• 872-05-9 1-Decene 
• 1666-13-3 diphenyl diselenide 
• 2179-79-5 phenyl selenocyanate 
• 112-29-8 1-bromo dodecane 
• 33861-17-5 phenyl trimethylsilyl selenide 
• 98750-95-9 (decylselenonyl)benzene 
• 645-96-5 Benzeneselenol 
• 2050-77-3 Iododecane 
• 23974-72-3 sodium phenylselenide 
• 22859-62-7 lithio-phenylselenyl-methane 
• 1002-69-3 decyl chloride 

Downstream Products

• 7289-52-3 1-methoxydecane 
• 872-05-9 1-Decene 
• 98750-95-9 (decylselenonyl)benzene 
• 112-30-1 1-Decanol 

Relevant articles and documents

α-Alkylation of tertiary amines by C(sp3)–C(sp3) cross-coupling under redox neutral photocatalysis

Direct α-alkylation of N-phenyl-tetrahydroisoquinoline with alkyl selenides of desired alkyl chain length and functionality is reported by photoredox catalysis. Construction of hexahydro pyrrolo- and pyrido-isoquinoline scaffolds along with indolines and tetrahydroquinolines is also described by intramolecular C(sp3)–C(sp3) cross-couplings.

A simple zinc-mediated preparation of selenols

Under acidic conditions zinc reduces diselenides to afford selenols, which can be either isolated or treated in situ with alkyl halides to produce alkyl selenides or with epoxides to give β-hydroxyselenides. Georg Thieme Verlag Stuttgart.

Reaction of organic selenocyanates with hydroxides: The one-pot synthesis of dialkyl diselenides from alkyl bromides

The amount of hydroxide used in the reaction with organic selenocyanate determines the identity of the product (see scheme). Dialkyl and diaryl diselenides are efficiently prepared with 0.5 equivalents of hydroxide, whereas the reaction of aryl selenocyanates with at least one molar equivalent of hydroxide leads to the formation of aryl selenolates, R = Ph, Bu, iPr, PhCH2; M = Li, Na, K.