61640-21-9Relevant articles and documents
Platinum-catalyzed domino reaction with benziodoxole reagents for accessing benzene-alkynylated Indoles
Li, Yifan,Waser, Jerome
supporting information, p. 5438 - 5442 (2015/04/27)
Indoles are omnipresent in natural products, bioactive molecules, and organic materials. Consequently, their synthesis or functionalization are important fields of research in organic chemistry. Most works focus on installation or modification of the pyrrole ring. To access benzene-ring-functionalized indoles with an unsubstituted pyrrole ring remains more challenging. Reported herein is a platinum-catalyzed cyclization/alkynylation domino process to selectively obtain C5- or C6-functionalized indoles starting from easily available pyrroles. The work combines, for the first time, a platinum catalyst with ethynylbenziodoxole hypervalent iodine reagents in a domino process for the synthesis of polyfunctionalized arene rings and gives access to important building blocks for the synthesis of bioactive compounds and organic materials.
Formation of stable neutral copper bis-dithiolene thin films by potentiostatic electrodeposition
Dalgleish, Simon,Awaga, Kunio,Robertson, Neil
supporting information; experimental part, p. 7089 - 7091 (2011/08/06)
Thin films of neutral copper dithiolenes have been prepared by potentiostatic electrodeposition. This method allows the isolation of near infrared (NIR) active species, in a useable form, that are otherwise unobtainable by conventional chemical methods.
CHEMICAL COMPOUNDS AND PROCESSES
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Page/Page column 55; 56, (2008/12/06)
The present invention relates generally to chemical compounds and methods for their use and preparation. In particular, the invention relates to chemical compounds which may possess useful therapeutic activity, use of these compounds in methods of therapy and the manufacture of medicaments as well as compositions containing these compounds.
