62246-53-1Relevant articles and documents
A new method for the synthesis of isothiocyanates from dithiocarbamates or alkyl amines using chlorosilanes as decomposition reagents
Bian, Gaofeng,Qiu, Huayu,Jiang, Jianxiong,Wu, Jirong,Lai, Guoqiao
, p. 503 - 508 (2007/10/03)
A series of isothiocyanates were prepared in good yields by the decomposition of dithiocarbamates using chlorosilanes such as Me 3SiCl, Me2SiCl2, MeSiCl3, and SiCl4 as decomposition reagents. Alkyl isothiocyanates were obtained by a facile one-pot method in high yield from alkyl amines using these inexpensive decomposition reagents in the presence of a base. Copyright Taylor & Francis Group, LLC.
A general synthesis of isothiocyanates from dithiocarbamates using claycop
Mesheram, Harashadas M.,Dale, Srinivas,Yadav
, p. 8743 - 8744 (2007/10/03)
A Convenient and simple synthesis of alkyl, aryl and amino acid isothiocyanates is described by the decomposition of ammonium dithiocarbamates using Claycop in mild conditions.
