62357-54-4

Basic information

• Product Name: 2,2,2-trichloro-1-[(1R,5R)-5-isopropenyl-2-methylcyclohex-2-en-1-yloxy]ethan-1-imine
• Synonyms: 2,2,2-trichloro-1-[(1R,5R)-5-isopropenyl-2-methylcyclohex-2-en-1-yloxy]ethan-1-imine
• CAS NO: 62357-54-4
• Molecular Weight: 296.624
• Mol File: 62357-54-4.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 2,2,2-trichloro-1-[(1R,5R)-5-isopropenyl-2-methylcyclohex-2-en-1-yloxy]ethan-1-imine(CAS DataBase Reference)
• NIST Chemistry Reference: 2,2,2-trichloro-1-[(1R,5R)-5-isopropenyl-2-methylcyclohex-2-en-1-yloxy]ethan-1-imine(62357-54-4)
• EPA Substance Registry System: 2,2,2-trichloro-1-[(1R,5R)-5-isopropenyl-2-methylcyclohex-2-en-1-yloxy]ethan-1-imine(62357-54-4)

Safety Data

• Hazardous Substances Data: 62357-54-4(Hazardous Substances Data)

Upstream product

• 99-48-9 (4R,6R)-carveol 
• 545-06-2 trichloroacetonitrile 

Downstream Products

• 62357-55-5 2,2,2-trichloro-N-[(1S,5S)-5-isopropenyl-2-methylcyclohex-2-en-1-yl]acetamide 

Relevant articles and documents

Synthesis and some transformations of (-)-carveol

Reduction of the oxo group in (-)-carvone with LiAlH4, NaBH4, and (i-Bu)2AlH was performed. It was found that the reduction with the system CeCl3 ? 7 H2O-NaBH4 in methanol at 20°C is the most practical procedure for the synthesis of (-)-carveol. Solvolysis of (-)-carvyl methanesulfonate gave products of SN2 and SN2' replacement of the methylsulfonyloxy group, the latter slightly prevailing. Overman rearrangement of (-)-carveol resulted in the formation of the corresponding trichloroacetamide derivative, and intramolecular iodoetherification of the title compound afforded 6-iodomethyl-2,6-dimethyl-7-oxabicyclo[3.2.1]oct-2-ene. Pleiades Publishing, Ltd., 2009.