6263-62-3Relevant articles and documents
Catenation of 2,2'-Bis(ethylthiomethyl)biphenyl with Copper(I) Bromide
Toyota, Shinji,Matsuda, Yohei,Oki, Michinori,Akashi, Haruo
, p. 31 - 32 (1995)
Treatment of 2-(ethylthiomethyl)phenyllithium with copper(I) bromide afforded a polymeric coordination compound in which 2,2'-bis(ethylthiomethyl)biphenyl molecules were linked by copper(I) bromide cores.This polymeric complex dissociates on dissolution in organic solvents and reforms on recrystalization from the solution.Other copper(I) salts also gave similar compounds, when reacted with the lithium compound.
Palladium- and Nickel-Catalyzed Decarbonylative C-S Coupling to Convert Thioesters to Thioethers
Ichiishi, Naoko,Malapit, Christian A.,Wo?niak, Aukasz,Sanford, Melanie S.
supporting information, p. 44 - 47 (2018/01/17)
This Letter describes the development of a catalytic decarbonylative C-S coupling reaction that transforms thioesters into thioethers. Both Pd- and Ni-based catalysts are developed and applied to the construction of diaryl, aryl alkyl, and heterocycle-containing thioethers.
Iodine-mediated thioetherification of alcohols with disulfides or NaSh under microwave irradiation
Hu, Bolun,Sun, Leilei,Tang, Riyuan,Hu, Huanan
, p. 2556 - 2562,7 (2020/09/16)
An efficient and novel method for the thioetherification of an alcohol with disulfides or NaSH under microwave irradiation is presented. In the presence of iodine, a variety of alcohols were smoothly S-alkylated with disulfides or NaSH to give the corresponding thioethers in moderate to excellent yields. Copyright