62793-31-1 Usage
General Description
The chemical BIS-1,5-CYCLOOCTADIENERHODIUM(L) HEXAFLjson.stringify({ : })UOROPHOSPHATE is a complex compound involving the metal rhodium. It is commonly used as a catalyst in organic synthesis reactions, particularly in the hydrogenation of alkenes and alkynes. BIS-1,5-CYCLOOCTADIENERHODIUM(L) HEXAFLUOROPHOSPHATE is known for its high efficiency and selectivity in catalyzing various types of chemical transformations. The hexafluorophosphate anion serves as a counterion to the rhodium complex, providing stability and solubility in organic solvents. BIS-1,5-CYCLOOCTADIENERHODIUM(L) HEXAFLUOROPHOSPHATE plays a crucial role in the development of new pharmaceuticals, agrochemicals, and other fine chemicals due to its unique catalytic properties.
Check Digit Verification of cas no
The CAS Registry Mumber 62793-31-1 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 6,2,7,9 and 3 respectively; the second part has 2 digits, 3 and 1 respectively.
Calculate Digit Verification of CAS Registry Number 62793-31:
(7*6)+(6*2)+(5*7)+(4*9)+(3*3)+(2*3)+(1*1)=141
141 % 10 = 1
So 62793-31-1 is a valid CAS Registry Number.
62793-31-1Relevant articles and documents
AZULENE AS A LIGAND IN CATIONIC RHODIUM AND IRIDIUM COMPLEXES. CRYSTAL STRUCTURE OF PF6
Oro, L.A.,Valderrama, M.,Cifuentes, P.,Foces-Foces, C.,Cano, F.H.
, p. 67 - 78 (2007/10/02)
Rhodium or iridium complexes of formula + have been prepared by treating 2 complexes with silver salts and azulene, and also by treating + with azulene.The reactions of some representative complexes have been studied.Reaction of 2+ with azulene appears to give dinuclear diazulene cationic complexes.The crystal structure of compound PF6 has been solved by X-ray methods.It crystallizes in the space group P21/c with cell constants 8.4241(4), 16.6911(8), 15.0026(7) Angstroem, 95.897(6) deg.Refinement gave R=0.027 and Rw=0.032 for 2991 observed reflexions.The Rh atom is coordinated to the five-membered ring, with Rh-C distances shortest for the atoms which are trans to the diolefinic double bonds.The bonding scheme within the azulene ligand differs from that in the parent hydrocarbon.
