6287-40-7

Basic information

• Product Name: DIBUTYLAMINE HYDROCHLORIDE
• Synonyms: Dibutylaminehydroc;dibutylammoniumchloride;Di-n-butylammoniumchlorid;N-butyl-1-butanaminehydrochloride;DIBUTYLAMINE HYDROCHLORIDE;dibutylamineHCl;Dibutylamine monohydrochloride
• CAS NO: 6287-40-7
• Molecular Formula: C₈H₂₀N*Cl
• Molecular Weight: 165.7
• EINECS: 228-521-0
• Mol File: 6287-40-7.mol
• Article Data: 5

Chemical Properties

• Melting Point: 284-286℃
• Boiling Point: 273.32°C (rough estimate)
• Flash Point: 41.1 °C
• Appearance: /
• Density: 0.9687 (rough estimate)
• Vapor Pressure: 2.1mmHg at 25°C
• Refractive Index: 1.5480 (estimate)
• CAS DataBase Reference: DIBUTYLAMINE HYDROCHLORIDE(CAS DataBase Reference)
• NIST Chemistry Reference: DIBUTYLAMINE HYDROCHLORIDE(6287-40-7)
• EPA Substance Registry System: DIBUTYLAMINE HYDROCHLORIDE(6287-40-7)

Safety Data

• Hazardous Substances Data: 6287-40-7(Hazardous Substances Data)

Usage

General Description

Dibutylamine hydrochloride is a chemical compound composed of dibutylamine, a colorless liquid with a fishy odor, and hydrochloric acid. It is commonly used as a catalyst in various chemical reactions, particularly in the production of rubber and plastics. Dibutylamine hydrochloride is also utilized as an intermediate in the manufacturing of pharmaceuticals and pesticides. Additionally, it is a corrosion inhibitor in oil and gas production and is employed in the synthesis of dyes and surfactants. The compound is considered to be hazardous, and caution should be exercised when handling it due to its toxic and irritant properties.

InChI:InChI=1/C8H19N.ClH/c1-3-5-7-9-8-6-4-2;/h9H,3-8H2,1-2H3;1H

Upstream product

• 999-33-7 N-chloro-N,N-dibutylamine 
• 111-92-2 dibutylamine 
• 64-19-7 acetic acid 
• 2391-80-2 Di-n-butylammonium di-n-butyldithiocarbamate 
• 7647-01-0 hydrogenchloride 
• 67-56-1 methanol 
• 27918-31-6 pentafluorobenzenesulfenyl chloride 
• 406679-89-8 α-isocyanatomethylmethyldimethoxysilane 
• 639-58-7 triphenyltin chloride 
• 1066-45-1 trimethyltin(IV)chloride 

Downstream Products

• 3529-09-7 n,n-di-n-butylethylenediamine 
• 619-37-4 N,N-di-n-butylurea 
• 924-16-3 N-nitrosodibutylamine 
• 4164-31-2 N-nitrodibutylamine 
• 79489-66-0 N¹,N¹-Dibutyl-N²-(p-tolyl)formamidine 
• 79489-67-1 N¹,N¹-Dibutyl-N²-(p-tolyl)acetamidine 
• 79489-61-5 2-Dibutylamino-6-methylquinoline 
• 110272-31-6 2-n-Propoxy-3-methoxy-β-dibutylamino-propiophenon 
• 96146-78-0 N,N-dibutyl-N'-cyano-guanidine 
• 749247-78-7 (Bu(n)2)2NH2[Ph2Sn(Cl)(μ2-mercaptoacetate)] 
• 111-92-2 dibutylamine 
• 1226878-18-7 C₈H₁₉N*C₃₂H₁₂BF₂₄^(1-)*H⁽¹⁺⁾ 
• 25033-65-2 N,N-dibutylbenzamide 

Relevant articles and documents

Synthesis, spectroscopic characterization and crystal and molecular structures of phenylphosphonato SnR3 (R=Ph, Me) derivatives

Four new phenylphosphonato SnR3 (R=Ph, Me) derivatives have been synthesized and characterized by infrared and Moessbauer spectroscopy. The structure of catena-poly[PhPO3HSnMe3]n has been determined by single-crystal X-ray diffraction analysis. The SnIV atoms are five-coordinated in all compounds, with the SnC3O 2 framework in a trans trigonal bipyramidal arrangement and the PhPO3H- anions being in axial positions. The molecular structure of [PhPO3HSnMe3]n is arranged as a one-dimensional coordination polymer in which planar SnMe3 groups are axially bridged by -O-P-O- linkages of the PhPO3H- ligand. Neighboring chains are linked via O-H...O hydrogen bond interactions, generating a layered structure. In the R2NH 2(PhPO3H)2SnR′3 (R=Cy, Bu; R′=Ph, Me), the SnPh3 or SnMe3 residue is axially coordinated by two monodentate PhPO3H-. The role of the dialkylammonium cation, R2NH2+, is crucial in the lattice building via a hydrogen bond network. These hydrogen bonds contribute to the crystal stability and compactness and result in a three-dimensional arrangement. The aqua complex PhPO3(SnPh 3)2·2H2O has a discrete structure and the anion PhPO32- behaves as a bidentate ligand.

Thermochemical properties of chelates of di-n-butyldithiocarbamate with phosphorus-group elements

The standard molar enthalpies of formation of crystalline tris(di-n-butyldithiocarbamato)E(III), (E = P, As, Sb, or Bi), determined at 298.15 K by solution-reaction calorimetry, are -(705.5 +/- 7.3), -(443.1 +/- 5.4), -(526.2 +/- 2.5), and -(530.7 +/- 5.5) kJ*mol-1, respectively.The enthalpies of sublimation: (136 +/- 3), (128 +/- 3), (179 +/- 3), and (202 +/- 3) kJ*mol-1, were estimated.From the enthalpies of formation of the gaseous complexes, the homolytic and heterolytic mean standard molar element-sulphur bond enthalpies were calculated.These values are correlated with element-sulphur bond distances, and a larger phosphorus- sulphur bond enthalpy reflects a better overlap of d orbitals in bonding formation.

Conversion of 2-dialkylamino-3H-azepines into epsilon caprolactams

This invention relates to a process of catalytically converting nitrobenzene to 2-amino-3H-azepines by the reaction of the nitrobenzene with trisaminophosphine and an amine of the formula HNR'2, where R' is lower alkyl containing 1 to 6 carbon atoms. In addition, this invention concerns the catalytic hydrogenation of 2-amino-3H-azepine to epsilon caprolactam.