6287-66-7Relevant articles and documents
Base-promoted reactions in ionic liquid solvents. The Knoevenagel and Robinson annulation reactions
Morrison, Doug W,Forbes, David C,Davis Jr., James H
, p. 6053 - 6055 (2001)
When used in place of classical organic solvents, ionic liquids offer a new and environmentally benign approach toward solvation in modern synthetic chemistry. Two classical named reactions, the Knoevenagel condensation and Robinson annulation, have been
Nylon monomer and preparation method thereof
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Paragraph 0028; 0031-0032, (2021/10/16)
The invention provides four nylon monomers and a preparation method thereof, wherein a nylon monomer is formed at 3 positions and 5 positions of a lactam or pimelic acid, and a preparation method of the nylon monomer is used for chalcone. The ethyl acetoa
Conversion of Simple Cyclohexanones into Catechols
Liang, Yu-Feng,Li, Xinyao,Wang, Xiaoyang,Zou, Miancheng,Tang, Conghui,Liang, Yujie,Song, Song,Jiao, Ning
supporting information, p. 12271 - 12277 (2016/09/28)
A novel I2-catalyzed direct conversion of cyclohexanones to substituted catechols under mild and simple conditions has been described. This novel transformation is remarkable with the multiple oxygenation and dehydrogenative aromatization processes enabled just by using DMSO as the solvent, oxidant, and oxygen source. This metal-free and simple system demonstrates a versatile protocol for the synthesis of highly valuable substituted catechols and therefore streamlines the synthesis and modification of biologically important molecules for drug discovery.