63082-55-3Relevant articles and documents
Pd(0)-catalyzed allylic alkylation/Heck coupling in domino sequence
Poli, Giovanni,Giambastiani, Giuliano,Pacini, Barbara
, p. 5179 - 5182 (2001)
A new molecular queuing process has been achieved, in which a single Pd-based catalytic system promotes two unrelated, sequential catalytic cycles in chronologically distinct order. This study demonstrates also that allylic alkylations can be catalyzed by the Herrmann's phosphapalladacycle, a result that further supports the involvement of a Pd(0) species in its mechanism of action.
Derivatives of phosphorous acid as a new class of ligands for Pd-catalyzed allylation
Moiseev,Lebedev,Polosukhin,Kalinin
, p. 554 - 556 (2001)
Amido- and aminophosphites and hydrospirophosphoranes can be used as ligands in the Pd-catalyzed allylation of ethyl malonate with ethyl (3-phenylprop-2-enyl) carbonate. Bidentate ligands (RO)2P - O(CH2)n - NR′2
Metal-free, regio- and stereoselective synthesis of linear (E)-allylic compounds using C, N, O, and S nucleophiles
Huang, Xiaojun,Fulton, Brandon,White, Kana,Bugarin, Alejandro
, p. 2594 - 2597 (2015/06/16)
A variety of allylic acetates and derivatives were synthesized by an efficient two-step protocol that employs readily available terminal alkenes as starting materials. This method is highly regio- and stereoselective, affording the linear (E)- isomer as the sole adduct. This process tolerates several functional groups including halogen-containing molecules, and it is general for weak oxygen, carbon, nitrogen, and sulfur nucleophiles. Furthermore, adducts were obtained in good to excellent yields.
Metathesis transformations of unsaturated derivatives of β-diketones
Mi?tkiewski, Mi?osz,Powa?a, Beata,Staniszewski, Bartosz,Kubicki, MacIej,Urbaniak, W?odzimierz,Pietraszuk, Cezary
scheme or table, p. 728 - 736 (2012/04/17)
Selected β-diketones bearing unsaturated derivatives have been demonstrated to undergo homo-metathesis and cross-metathesis with selected olefins in the presence of Grubbs catalysts. The reactions led to respective homo- and cross-metathesis products mainly with good yields and selectivities. Versita Sp. z o.o.