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63553-62-8

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63553-62-8 Usage

Check Digit Verification of cas no

The CAS Registry Mumber 63553-62-8 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 6,3,5,5 and 3 respectively; the second part has 2 digits, 6 and 2 respectively.
Calculate Digit Verification of CAS Registry Number 63553-62:
(7*6)+(6*3)+(5*5)+(4*5)+(3*3)+(2*6)+(1*2)=128
128 % 10 = 8
So 63553-62-8 is a valid CAS Registry Number.

63553-62-8Relevant articles and documents

Kinetic Resolution of α-Silyl-Substituted Allylboronate Esters via Chemo- and Stereoselective Allylboration of Aldehydes

Park, Jinyoung,Jung, Yongsuk,Kim, Jeongho,Lee, Eunsung,Lee, Sarah Yunmi,Cho, Seung Hwan

supporting information, p. 2371 - 2376 (2020/12/01)

We describe the kinetic resolution of α-silyl-substituted allylboronate esters via chiral phosphoric acid-catalyzed chemo-, diastereo- and enantioselective allylboration of aldehydes. This process provides two synthetically versatile enantioenriched compo

Bi(cyclopentyl)diol-Derived Boronates in Highly Enantioselective Chiral Phosphoric Acid-Catalyzed Allylation, Propargylation, and Crotylation of Aldehydes

Yuan, Jinping,Jain, Pankaj,Antilla, Jon C.

, p. 12988 - 13003 (2020/11/23)

In this study, we disclose the catalytic addition of bi(cyclopentyl)diol-derived boronates to aldehydes promoted by chiral phosphoric acids, allowing for the formation of enantioenriched homoallylic, propargylic, and crotylic alcohols (up to >99% enantiom

Stereodivergent total synthesis of Br-nannocystins underpinning the polyketide (10R,11S) configuration as a key determinant of potency

Tian, Yunfeng,Wang, Jiyan,Liu, Wenjie,Yuan, Xiaoya,Tang, Yang,Li, Jing,Chen, Yue,Zhang, Weicheng

, p. 568 - 578 (2019/01/21)

Continuing our investigation into the structure-activity relationship of antiproliferative macrocyclic nannocystins, we describe herein total synthesis of all four stereoisomers of Br-nannocystins as well as a simplified analogue varying at the polyketide C10 and C11 positions. Biological evaluation of these compounds against PANC1 cancer cell lines showed that both the (10R,11S) configuration and its associated two substituents are crucial for high potency.

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