64284-54-4Relevant articles and documents
Synthesis, structure, and catalytic activity of palladium complexes bearing a tridentate PXP-pincer ligand of heavier group 14 element (X = Ge, Sn)
Takaya, Jun,Nakamura, Shuhei,Iwasawa, Nobuharu
supporting information, p. 967 - 969 (2012/11/07)
An efficient method for the synthesis of tridentate PGeP- and PSnP-palladium complexes is developed. Structural analysis revealed that PSiP-ligand exerts the strongest trans influence and electron donation and that PGeP- and PSnP-ligands provide wider coordination sphere around the palladium. Preliminary studies demonstrated that both PGeP- and PSnP-palladium complexes work as an efficient catalyst for reductive aldol-type reaction, indicating promising utility in synthetic organic chemistry.