64634-57-7

Basic information

• Product Name: Benzenamine, 4-fluoro-N,N-bis(4-methylphenyl)-
• CAS NO: 64634-57-7
• Molecular Formula: C20H18FN
• Molecular Weight: 291.368
• Mol File: 64634-57-7.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: Benzenamine, 4-fluoro-N,N-bis(4-methylphenyl)-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzenamine, 4-fluoro-N,N-bis(4-methylphenyl)-(64634-57-7)
• EPA Substance Registry System: Benzenamine, 4-fluoro-N,N-bis(4-methylphenyl)-(64634-57-7)

Safety Data

• Hazardous Substances Data: 64634-57-7(Hazardous Substances Data)

Upstream product

• 352-33-0 1-Chloro-4-fluorobenzene 
• 620-93-9 di-p-tolylamine 
• 352-34-1 4-fluoro-1-iodobenzene 
• 106-43-4 para-chlorotoluene 
• 371-40-4 4-fluoroaniline 

Relevant articles and documents

Nickel-catalyzed triarylamine synthesis: Synthetic and mechanistic aspects

An improved protocol was described for the amination of chloroarenes with diarylamines under NiCl2(PCy3)2 catalysis in the presence of a Grignard reagent as base. This method fully suits bromo-/iodoarene substrates as well, and even is expanded to certain aryl tosylates. A preliminary investigation into the mechanism suggests that this amination reaction might proceed through NiI and NiIII intermediates rather than via the usually expected Ni0-Ni II cycle.