64677-34-5Relevant articles and documents
Electrocatalytic Activation of Donor–Acceptor Cyclopropanes and Cyclobutanes: An Alternative C(sp3)?C(sp3) Cleavage Mode
Brandt, Felix,Jacob, Christoph R.,Jones, Peter G.,Kolb, Simon,Petzold, Martin,Werz, Daniel B.
supporting information, p. 15928 - 15934 (2021/06/21)
We describe the first electrochemical activation of D–A cyclopropanes and D–A cyclobutanes leading after C(sp3)?C(sp3) cleavage to the formation of highly reactive radical cations. This concept is utilized to formally insert molecula
Regioselective oxidative ring-opening of cyclopropenyl carboxylates by visible light photoredox catalysis
Ye, Qianwen,Ye, Hongqiang,Cheng, Dongping,Li, Xiaonian,Xu, Xiaoliang
, p. 2546 - 2549 (2018/05/28)
Catalyzed by Ir(dFCF3ppy)2(dtbbpy)PF6, several aroyl methylidenemalonates were synthesized in good to excellent yields via visible light photoredox-catalyzed the oxidative ring-opening of cyclopropenyl carboxylate derivatives. The possible mechanism of oxidative quenching cycle was proposed.