64678-87-1Relevant articles and documents
Dual pathways for the desilylation of silylamines by singlet oxygen
Baciocchi, Enrico,Del Giacco, Tiziana,Lapi, Andrea
, p. 1783 - 1786 (2007/10/03)
A kinetic and product study has been carried out for the reactions of silylamines 1a and 1b with 1O2 in MeCN and (80:20) MeCN-MeOH. Indications suggesting an electron-transfer step following exciplex (I) formation have been obtained. However, the fate of the radical cation is solvent dependent. The radical cation undergoes desilylation in MeCN-MeOH and deprotonation in MeCN.