65044-35-1 Usage
Description
Pyrrolidinium, 1-(chlorophenylmethylene)-, chloride is a pyrrolidinium salt with the molecular formula C11H11ClN. It is a white to off-white powder that is soluble in organic solvents. This chemical compound is known for its versatile and diverse applications in chemical synthesis and research, making it a valuable tool in the field of organic chemistry.
Uses
Used in Organic Synthesis:
Pyrrolidinium, 1-(chlorophenylmethylene)-, chloride is used as a catalyst in various organic reactions. Its ability to facilitate and enhance the efficiency of these reactions makes it a valuable component in the synthesis of complex organic molecules.
Used in Pharmaceutical Industry:
Pyrrolidinium, 1-(chlorophenylmethylene)-, chloride is used as an intermediate in the synthesis of pharmaceutical compounds. Its role in the production of various drugs highlights its importance in the development of new and effective medications.
Used in Chemical Research:
Pyrrolidinium, 1-(chlorophenylmethylene)-, chloride is also utilized in chemical research to explore new reaction pathways and develop innovative synthetic methods. Its diverse applications in research contribute to the advancement of organic chemistry.
Check Digit Verification of cas no
The CAS Registry Mumber 65044-35-1 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 6,5,0,4 and 4 respectively; the second part has 2 digits, 3 and 5 respectively.
Calculate Digit Verification of CAS Registry Number 65044-35:
(7*6)+(6*5)+(5*0)+(4*4)+(3*4)+(2*3)+(1*5)=111
111 % 10 = 1
So 65044-35-1 is a valid CAS Registry Number.
65044-35-1Relevant articles and documents
Frustrated Lewis Pair Catalyzed Hydrogenation of Amides: Halides as Active Lewis Base in the Metal-Free Hydrogen Activation
Sitte, Nikolai A.,Bursch, Markus,Grimme, Stefan,Paradies, Jan
, p. 159 - 162 (2019/01/04)
A method for the metal-free reduction of carboxylic amides using oxalyl chloride as an activating agent and hydrogen as the final reductant is introduced. The reaction proceeds via the hydrogen splitting by B(2,6-F2-C6H3)3 in combination with chloride as the Lewis base. Density functional theory calculations support the unprecedented role of halides as active Lewis base components in the frustrated Lewis pair mediated hydrogen activation. The reaction displays broad substrate scope for tertiary benzoic acid amides and α-branched carboxamides.
Reactions of Relevance to the Chemistry of Aminoglycoside Antibiotics. Part 13. A Novel Synthesis of Benzyl Ethers
Barrett, Anthony G. M.,Read, Roger W.,Barton, Derek H. R.
, p. 2184 - 2190 (2007/10/02)
Benzyl ethers were prepared from alcohols by reaction with chloro(phenylmethyl)dimethylammonium chloride and sodium hydrogen telluride in sequence.The salt (1) 1)OR2Cl-; R1=H, R2=cholest-5-en-3β-yl> and sodium borohydride gave the borane complex of 3β-dimethylaminomethoxycholest-5-ene.Salt (1; R1=Ph, R2=cholest-5-en-3β-yl or 5α-cholestan-3β-yl) and ammonia or hydrazine gave the steroidal benzimidates or benzhydrazonate.
