65332-44-7Relevant articles and documents
Visible-light C-heteroatom bond cleavage and detoxification of chemical warfare agents using titania-supported gold nanoparticles as photocatalyst
Neau, Tefan,Cojocaru, Bogdan,Parvulescu, Vasile I.,Omoghi, Vasile,Alvaro, Mercedes,Garcia, Hermenegildo
supporting information; scheme or table, p. 4050 - 4054 (2011/07/29)
Gold nanoparticles supported on TiO2 effect the detoxification of soman and VX nerve gases and yperite vesicant agent at room temperature upon visible light illumination.
&β-(N,N-Dialkylamino)ethyl Arylthiosulfonates: New Simulants for O-Ethyl S- Methylphosphonothioate
Davis, Franklin A.,Ray, Jayanta K.,Kasperowicz, Steve,Przeslawski, Robert M.,Durst, H. Dupont
, p. 2594 - 2599 (2007/10/02)
β-(N,N-Dialkylamino)ethyl arylthiosulfonates 2, new simulants for the hydrolysis and oxidation chemistry of VX (1), are prepared in good yield by reaction of a potassium arylthiosulfonate with a 2-chloroethylamine.Alkaline hydrolysis of 2 results in cleavage of the S-S-bond to give sulfinic acids and disulfides.Like VX, oxidation of 2 by N-sulfonyloxaziridine 12 occurs exclusively on nitrogen to give the corresponding amine oxide which subsequently undergoes a Cope elimination reaction affording the vinyl sulfide 14.