65578-58-7

Basic information

• Product Name: 1,2-Hydrazinedicarboxylic acid, 1-phenyl-, bis(1,1-dimethylethyl) ester
• CAS NO: 65578-58-7
• Molecular Formula: C16H24N2O4
• Molecular Weight: 308.378
• Mol File: 65578-58-7.mol
• Article Data: 17

Chemical Properties

• CAS DataBase Reference: 1,2-Hydrazinedicarboxylic acid, 1-phenyl-, bis(1,1-dimethylethyl) ester(CAS DataBase Reference)
• NIST Chemistry Reference: 1,2-Hydrazinedicarboxylic acid, 1-phenyl-, bis(1,1-dimethylethyl) ester(65578-58-7)
• EPA Substance Registry System: 1,2-Hydrazinedicarboxylic acid, 1-phenyl-, bis(1,1-dimethylethyl) ester(65578-58-7)

Safety Data

• Hazardous Substances Data: 65578-58-7(Hazardous Substances Data)

Upstream product

• 24424-99-5 di-tert-butyl dicarbonate 
• 42116-43-8 tert-butyl 2-phenylhydrazine-1-carboxylate 
• 870-50-8 di-tert-butyl-diazodicarboxylate 
• 591-51-5 phenyllithium 
• 312934-60-4 1,1,2-tris(tert-butoxycarbonyl)-2-phenylhydrazine 
• 16466-61-8 1,2-bis(t-butyloxycarbonyl)hydrazine 
• 28899-97-0 triphenylbismuth(V) diacetate 
• 870-46-2 t-butoxycarbonylhydrazine 
• 98-80-6 phenylboronic acid 
• 960-16-7 tributylphenylstannane 
• 870-50-8 di-tert-butyl (E)-azodicarboxylate 
• 603-33-8 triphenylbismuthane 
• 591-50-4 iodobenzene 
• 780-69-8 triethoxyphenylsilane 

Downstream Products

• 59-88-1 phenylhydrazine hydrochloride 
• 312934-66-0 1,2-Bis(t-butyloxycarbonyl)-2-(4-methylphenyl)-1-phenylhydrazine 
• 20488-61-3 trans-4-nitroazobenzene 
• 17082-12-1 trans-azobenzene 
• 875537-66-9 (E)-1-[4-(phenyldiazenyl)phenyl]ethanone 
• 15516-69-5 (E)-1-(4-(tert-butyl) phenyl)-2-phenyldiazene 
• 6720-39-4 trans-phenyl-p-tolyl-diazene 
• 36369-22-9 1,4-bis-(phenyl-trans-azo)-benzene 
• 21650-49-7 (E)-1-(4-methoxyphenyl)-2-phenyldiazene 
• 55669-57-3 3-Cyanoazobenzol 
• 92594-44-0 (E)-4-(phenyldiazenyl)benzonitrile 
• 7466-42-4 4-(Phenylazo)-biphenyl 
• 119479-29-7 methyl 4-(phenyldiazenyl)benzoate 
• 828246-94-2 C₂₅H₃₂N₂O₆ 

Relevant articles and documents

Preparation method of silver-mediated N-arylhydrazine compound

The invention relates to a preparation method of an N-aryl hydrazide compound, which comprises the following steps: adding AgF, a reactant I, a reactant II, butanone and a magneton 5 into a reactor in sequence, connecting a condenser pipe, introducing condensate water from bottom to top, placing the reactor in an oil bath pan at 30-70 DEG C, heating, stirring and reacting for 10-12 hours, terminating the reaction, and purifying the product to obtain the N-aryl hydrazide compound. The method is mild in reaction condition, high in selectivity, relatively high in yield and environment-friendly; and the compound has certain biological activity and can be used in the field of synthesis of drugs, pesticides and paint dyes.

Diaza [1,4] Wittig-type rearrangement of N-allylic-N-Boc-hydrazines into γ-amino- N -Boc-enamines

Diaza [1,4] Wittig-type rearrangement of N-allylic-N-Boc-hydrazines into γ-amino-N-Boc-enamines was demonstrated. The scope and limitation, experimental mechanistic studies, and a proposed reaction mechanism were also described.

Amination of Arylboronic Compounds via the Copper-Catalyzed Addition of Arylboronic Esters to Azodicarboxylates

Arylboronic esters add to di-tert-butyl azodicarboxylate under mild reaction conditions (at room temperature) to afford aryl-substituted hydrazine derivatives in good yields. The reaction tolerates a wide variety of functional groups.