6591-42-0Relevant articles and documents
Intramolecular nucleophilic substitution of ω-haloalkylphosphine derivatives
Pawe?, Wo?nicki,Korzeniowska, Ewelina,Stankevic, Marek
, p. 10271 - 10296 (2018/02/27)
ω-Haloalkylphosphine derivatives undergo the intramolecular nucleophilic substitution reaction upon treatment with a strong base, yielding either cycloalkylphosphine derivatives or heterocyclic phosphine derivatives. The selectivity of the cyclization of
Radical phosphination of organic halides and alkyl imidazole-1- carbothioates
Sato, Akinori,Yorimitsu, Hideki,Oshima, Koichiro
, p. 4240 - 4241 (2007/10/03)
Taking advantage of a radical-based methodology, mild and chemoselective phosphination reactions of organic halide and alkyl imidazole-1-carbothioates have been developed. The mild reaction conditions allow labile functional groups to survive during the reaction. Copyright
Palladium-catalyzed synthesis of vinyl phosphines from ketones
Gilbertson, Scott R.,Fu, Zice,Starkey, Gale W.
, p. 8509 - 8512 (2007/10/03)
The palladium-catalyzed conversion of vinyl triflates to vinyl phosphines is reported. This process allows for the synthesis of vinyl phosphines from ketones. Selective enolization of a variety of ketones followed by trapping of the enolate as the vinyl triflate is reported. The vinyl triflates are then converted to the corresponding vinyl phosphine through palladium catalysis. The resulting vinyl phosphines can then be reduced to give alkyl phosphines.