661-53-0Relevant articles and documents
Determination and interpretation of second order rate constants for the addition of hydrogen halides to alkenes
Borgeaud, Robert,Newman, Henry,Schelpe, Arabella,Vasco, Veronica,Peter Hughes
, p. 810 - 813 (2007/10/03)
An extensive range of second order rate constants for the addition of hydrogen halides to alkenes in 98% v/v ethanoic acid (acetic acid)-water have been obtained by conductivity measurements. The rate constants are in the expected order of HF HCl HBr HI. The rates with different alkenes cannot be rationalised solely by a consideration of carbocation stability and it has been necessary to consider steric effects in order to explain the observed order.