66130-01-6

Basic information

• Product Name: Benzenemethanol, a-(1-methylpropyl)-a-phenyl-
• CAS NO: 66130-01-6
• Molecular Formula: C17H20O
• Molecular Weight: 240.345
• Mol File: 66130-01-6.mol
• Article Data: 6

Chemical Properties

• CAS DataBase Reference: Benzenemethanol, a-(1-methylpropyl)-a-phenyl-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzenemethanol, a-(1-methylpropyl)-a-phenyl-(66130-01-6)
• EPA Substance Registry System: Benzenemethanol, a-(1-methylpropyl)-a-phenyl-(66130-01-6)

Safety Data

• Hazardous Substances Data: 66130-01-6(Hazardous Substances Data)

Upstream product

• 116-53-0 2-Methylbutanoic acid 
• 868-57-5 methyl 2-methylbutanoate 
• 100-58-3 phenylmagnesium bromide 
• 119-61-9 benzophenone 
• 671795-46-3 sec-butylmagnesium bromide 
• 78-86-4 s-butyl chloride 
• 78-76-2 s-butyl bromide 
• 1113-78-6 tri(sec-butyl)borane 
• 591-51-5 phenyllithium 
• 18516-19-3 2,2-dimethyl-3-oxopropyl 4-methylbenzenesulfonate 
• 5856-79-1 iso-butyl chloroformate 

Downstream Products

• 26465-78-1 (2-methylbutane-1,1-diyl)dibenzene 
• 66129-95-1 (2-methylbut-1-ene-1,1-diyl)dibenzene 
• 101-53-1 p-benzylphenol 
• 135-98-8 sec-Butylbenzene 

Relevant articles and documents

Iron-catalysed 1,2-aryl migration of tertiary azides

1,2-Aryl migration of α,α-diaryl tertiary azides was achieved by using the catalytic system of FeCl2/N-heterocyclic carbene (NHC) SIPr·HCl. The reaction generated aniline products in good yields after one-pot reduction of the migration-resultant imines.

Highly efficient alkylation to ketones and aldimines with Grignard reagents catalyzed by zinc(II) chloride

A highly efficient alkylation to ketones and aldimines with Grignard reagents in the presence of catalytic trialkylzinc(II) ate complexes derived from ZnCl2 (10 mol %) in situ was developed. This simple Zn(II)-catalyzed alkylation could minimize the well-known but serious problems with the use of only Grignard reagents, which leads to reduction and aldol side products, and the yield of desired alkylation products could be improved. Copyright

Electrochemical alkyl transfer reactions of trialkylborane to carbonyl compounds by use of copper sacrificial anode

Alkyl groups in trialkylboranes were successfully transferred to carbonyl compounds in the presence of the platinum cathode and copper anode by electrochemical method. The new, mild electrochemical alkyl transfer reaction produced various substituted alcohols in good yields.