6655-34-1

Basic information

• Product Name: 4,5,6,7,8,8-hexachloro-2-propoxy-3a,4,7,7a-tetrahydro-1H-4,7-methanoisoindole-1,3(2H)-dione
• CAS NO: 6655-34-1
• Molecular Formula: C₁₄H₁₃N₃O₅S
• Molecular Weight: 427.9228
• Mol File: 6655-34-1.mol
• Article Data: 1

Chemical Properties

• Boiling Point: 454°C at 760 mmHg
• Flash Point: 228.3°C
• Density: 1.77g/cm³
• Vapor Pressure: 1.98E-08mmHg at 25°C
• Refractive Index: 1.628
• CAS DataBase Reference: 4,5,6,7,8,8-hexachloro-2-propoxy-3a,4,7,7a-tetrahydro-1H-4,7-methanoisoindole-1,3(2H)-dione(CAS DataBase Reference)
• NIST Chemistry Reference: 4,5,6,7,8,8-hexachloro-2-propoxy-3a,4,7,7a-tetrahydro-1H-4,7-methanoisoindole-1,3(2H)-dione(6655-34-1)
• EPA Substance Registry System: 4,5,6,7,8,8-hexachloro-2-propoxy-3a,4,7,7a-tetrahydro-1H-4,7-methanoisoindole-1,3(2H)-dione(6655-34-1)

Safety Data

• Hazardous Substances Data: 6655-34-1(Hazardous Substances Data)

Upstream product

• 5906-99-0 2-nitrobenzenesulfonyl hydrazide 
• 123-11-5 4-methoxy-benzaldehyde 
• 1694-92-4 2-Nitrobenzenesulfonyl chloride 

Downstream Products

• 24393-56-4 ethyl (E)-3-(4-methoxyphenyl)prop-2-enoate 
• 51507-22-3 (Z)-ethyl 3-(4-methoxyphenyl)acrylate 

Relevant articles and documents

Silver-Catalyzed Cross-Olefination of Donor and Acceptor Diazo Compounds: Use of N-Nosylhydrazones as Diazo Surrogate

The cross-olefination reaction of donor and acceptor diazo compounds was explored. The use of N-nosylhydrazones as diazo surrogates and the dependence on silver catalysis were crucial for the reaction development. A variety of (hetero)aryl N-nosylhydrazones and α-diazo esters, amides, and phosphonates were compatible, and the functionalized alkene products were afforded in good to high yields with moderate (Z)/(E) selectivities. The experimental and DFT calculation results suggest that the cross-selectivity is due to selective activation of the silver catalyst for donor diazo compounds.