66760-15-4Relevant articles and documents
Synthesis, reactions, and spectral [NMR(1H, 13C, and 29Si), IR] studies of organosilicon aryloxides
Mishra,Singh
, p. 772 - 774 (2007/10/03)
Organosilicon aryloxides of the types MeaSi(OAr) and MeSi(OAr)3 (Ar = C6H4Bus-2; C6H3Me-2-Pri-5; C6H3Me-5-Pri-2) have been prepared, respectively, from reactions of appropriate phenols with Me3SiCl or MeSiCl3 in benzene using Et3N as a base. Reactions of Me3Si(OAr) with TiCl4 in 1:1 and 2:1 molar ratios in benzene afford derivatives TiCl3(OAr) and TiCl2(OAr)2, respectively. All these new derivatives have been characterized by elemental analyses, spectroscopic [IR, NMR (1H, 13C, and 29Si)] studies, as well as by molecular weight measurements.