6721-33-1Relevant articles and documents
Two novel organic-inorganic hybrid compounds with straight and zigzag chain alignments of Cu(II) centers: Synthesis, crystal structure, spectroscopy, thermal analysis and magnetism
Nenwa, Justin,Djomo, Edith D.,Nfor, Emmanuel N.,Djonwouo, Patrick L.,Mbarki, Mohammed,Fokwa, Boniface P.T.
, p. 26 - 33 (2015/07/15)
Abstract Two hybrid salts, viz. bis(guanidinium) bis(oxalato)cuprate(II) (1) and bis(2-aminopyridinium) bis(oxalato)cuprate(II) trihydrate (2) have been synthesized and characterized by elemental and thermal analyses, IR spectroscopy, single-crystal X-ray diffraction and SQUID magnetometry. Compounds 1 and 2 crystallize in the monoclinic P21/c and triclinic P1ˉ space groups, respectively. In both structures, the four-coordinated Cu(II) ion in [Cu(C2O4)2]2- unit weakly interacts with two axial O-atoms of neighboring units to build a prolate CuO6 octahedron, with regular axial Cu-O bonds of 2.825 ? in 1, whereas in 2 two different Cu-O bonds (2.814 ? and 2.701 ?) are found. In 1, stacking of [Cu(C2O4)2]2- units across internal symmetry-related O-atoms results in equidistantly spaced monomers, thus forming straight Cu(II) chains with regular spacing of Cu?Cu = 3.582 ?. By contrast, in 2, stacking of the [Cu(C2O4)2]2- entities occurs via external symmetry-related O-atoms, yielding zigzag Cu(II) chains with shorter intra-dimer spacing of [Cu?Cu]intra = 3.430 ? and longer inter-dimer spacing of [Cu?Cu]inter = 4.961 ?. The anhydrated compound 1 is stable up to 250 °C, whereas the hydrated compound 2 shows a significant weight loss of solvent water molecules at about 70°C, followed by the decomposition of the network. The magnetic measurements in the 2-300 K temperature range revealed weak antiferromagnetic coupling in the two hybrid salts.
Analysis of the CO2 and NH3 reaction in an aqueous solution by 2D IR COS: Formation of bicarbonate and carbamate
Park, HoSeok,Jung, Young Mee,You, Jong Kyun,Hong, Won Hi,Kim, Jong-Nam
, p. 6558 - 6562 (2009/04/13)
The two-dimensional (2D) infrared correlation spectra obtained from the reaction time- and concentrationdependent IR spectra elucidates the reaction of CO2 and NH3 in an aqueous solution for CO2 absorption. In the synchron
ENZYMATIC DECOMPOSITION OF CARBAMIDE WITH IMMOBILIZED UREASE
Berezina, N. P.,Kononenko, N. A.,Ivina, O. P.,Vitul'skaya, N. V.,Shamolina, I. A.
, p. 372 - 375 (2007/10/02)
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