67990-76-5 Usage
General Description
1,1,2,2-Tetrafluoro-2-(1,1,2,2,3,3,4,4-octafluoro-4-iodobutoxy)ethanesulfonyl fluoride, also known as TFIBS, is a chemical compound with the molecular formula C8F18IO4S. It is a highly reactive and corrosive compound that is primarily used as a fluorinating and sulfonylating agent in organic synthesis. TFIBS is a clear, colorless liquid that is soluble in organic solvents and has a sharp, acrid odor. It is known for its strong oxidizing properties and is used in a variety of industrial applications, including the production of specialty chemicals and pharmaceuticals. TFIBS is also used as a reagent in chemical research and has been the subject of numerous studies for its potential applications in various fields.
Check Digit Verification of cas no
The CAS Registry Mumber 67990-76-5 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 6,7,9,9 and 0 respectively; the second part has 2 digits, 7 and 6 respectively.
Calculate Digit Verification of CAS Registry Number 67990-76:
(7*6)+(6*7)+(5*9)+(4*9)+(3*0)+(2*7)+(1*6)=185
185 % 10 = 5
So 67990-76-5 is a valid CAS Registry Number.
InChI:InChI=1/C6F13IO3S/c7-1(8,3(11,12)20)2(9,10)4(13,14)23-5(15,16)6(17,18)24(19,21)22
67990-76-5Relevant articles and documents
PERFLUORO-ω-IODO-3-OXAALKANESULFONYL FLUORIDES AS INTERMEDIATES FOR SURFACTANTS AND VINYL COMPOUNDS
Bargigia, G. A.,Caporiccio, G.,Pianca, M.
, p. 403 - 410 (2007/10/02)
Fluorosulfonyldifluoroacetyl fluoride (FOCCF2SO2F) quantitatively formed from sulfur trioxide and TFE through tetrafluoroethanesultone, has been converted into the octafluoro-5-iodo-3-oxapentanesulfonyl fluoride (ICF2CF2OCF2CF2SO2F) by the well known reaction involving MF, iodine and TFE in aprotic solvents.The iodo compound allowed us to obtain TFE telomers having both fluorosulfonyl and iodo terminal groups.These telomers were easily converted into the surfactants CF3CF2(CF2CF2)nOCF2F2SO3M by fluorination, and into the vinyl derivatives CF2=CF(CF2CF2)nOCF2CF2SO2F by dehalogenation.The scope of this study was to illustrate new methods for the synthesis of perfluoroalkane and perfluoroalkene sulfonates.