68089-86-1 Usage
Description
(CHLOROMETHYL)TRIPHENYLPHOSPHONIUM IODIDE is a quaternary ammonium salt with the molecular formula C19H17ClIP. It is a white crystalline solid that is highly soluble in polar solvents such as acetonitrile and methanol. This chemical compound is commonly used in organic synthesis as a source of the chloromethyl cation.
Uses
Used in Organic Synthesis:
(CHLOROMETHYL)TRIPHENYLPHOSPHONIUM IODIDE is used as a source of the chloromethyl cation for the formation of carbon-carbon and carbon-heteroatom bonds. It is a useful reagent in the preparation of various organic compounds.
Used as a Phase-Transfer Catalyst:
In the field of organic reactions, (CHLOROMETHYL)TRIPHENYLPHOSPHONIUM IODIDE is used as a phase-transfer catalyst to facilitate reactions between reactants in different phases, improving the efficiency and selectivity of the process.
Used in Pharmaceutical and Medical Research:
(CHLOROMETHYL)TRIPHENYLPHOSPHONIUM IODIDE has been studied for its potential use in pharmaceuticals and medical research, although specific applications have not been detailed in the provided materials.
Check Digit Verification of cas no
The CAS Registry Mumber 68089-86-1 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 6,8,0,8 and 9 respectively; the second part has 2 digits, 8 and 6 respectively.
Calculate Digit Verification of CAS Registry Number 68089-86:
(7*6)+(6*8)+(5*0)+(4*8)+(3*9)+(2*8)+(1*6)=171
171 % 10 = 1
So 68089-86-1 is a valid CAS Registry Number.
InChI:InChI=1/C19H17ClP.HI/c20-16-21(17-10-4-1-5-11-17,18-12-6-2-7-13-18)19-14-8-3-9-15-19;/h1-15H,16H2;1H/q+1;/p-1
68089-86-1Relevant articles and documents
SUBSTITUTION OF THE ANION IN AMMONIUM AND PHOSPHONIUM CHLORIDES BY THE ACTION OF ELECTROPHILIC AGENTS
Kukhar', V. P.,Pasternak, V. I.,Shevchenko, I. V.,Shevchenko, M. V.,Marchenko, A. P.,Makovetskii, Yu. P.
, p. 161 - 166 (2007/10/02)
N,N-Dialkylmethaniminium iodides were obtained by the reactions of N,N-dialkylmethaniminium chlorides with methyl iodide.The reactions of ammonium and phosphonium chlorides with triethyloxonium tetrafluoroborate, dimethyl sulfate, methyl tosylate, and methyl iodide take place with substitution of the chloride ion by the BF4-, CH3SO3O-, p-CH3C6H4SO3- or I- ions.Substitution of the chloride ion of phosphonium salts by the iodide ion can be realized by the action of trimethyliodosilane.
