68157-27-7

Basic information

• Product Name: adamantan-2-yl(phenyl)methanone
• Synonyms: adamantan-2-yl(phenyl)methanone
• CAS NO: 68157-27-7
• Molecular Weight: 240.345
• Mol File: 68157-27-7.mol
• Article Data: 9

Chemical Properties

• CAS DataBase Reference: adamantan-2-yl(phenyl)methanone(CAS DataBase Reference)
• NIST Chemistry Reference: adamantan-2-yl(phenyl)methanone(68157-27-7)
• EPA Substance Registry System: adamantan-2-yl(phenyl)methanone(68157-27-7)

Safety Data

• Hazardous Substances Data: 68157-27-7(Hazardous Substances Data)

Upstream product

• 700-58-3 2-Adamantanone 
• 31675-43-1 diethyl 1-phenyl-1-(trimethylsiloxy)methanephosphonate 
• 35856-00-9 2-adamantanecarbonitrile 
• 591-51-5 phenyllithium 
• 40079-92-3 2-adamantanecarbonyl chloride 
• 71-43-2 benzene 
• 53140-72-0 2-adamantyl(phenyl)methanol 
• 113849-79-9 1-(2-Adamantylidene)-1-methoxy-1-phenylmethane 
• 98-88-4 benzoyl chloride 
• 6343-27-7 1-benzoylpyrrolidine-2,5-dione 
• 281-23-2 adamantane 
• 7314-85-4 2-adamantyl bromide 
• 15897-81-1 adamantane-2-carboxylic acid 
• 72590-63-7 2-(methoxymethylene)adamantane 

Downstream Products

• 53140-72-0 2-adamantyl(phenyl)methanol 
• 219812-03-0 2-benzoyl-2-methyladamantane 
• 113849-79-9 1-(2-Adamantylidene)-1-methoxy-1-phenylmethane 

Relevant articles and documents

ELECTRON-TRANSFER INDUCED CONVERSION OF ENOL-ETHERS INTO KETONES

Alkoxy (aryl)-methylidene adamantanes react with catalytic amounts of tris p-bromophenylammoniumyl hexachloroantimonate in CH2Cl2 under argon atmosphere, yielding adamantyl-arylketones together with the corresponding alcohols.The reaction most likely proc

Adamantylzinc bromides: Direct preparation and application to cross-coupling reaction

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Enhanced enantio- and diastereoselectivity via confinement and cation binding: Yang photocyclization of 2-benzoyladamantane derivatives within zeolites

Irradiation of 2-benzoyladamantane derivatives in zeolites yields the endo-cyclobutanols as the only photoproduct via a γ-hydrogen abstraction process. The cyclobutanols readily undergo retroaldol reaction to give δ-ketoesters. The enantiomeric excess (ee) in the endo-cyclobutanols is measured by monitoring the ee in the ketoesters. Whereas in solution the ee in the product ketoester is zero, within achiral NaY zeolite, in the presence of a chiral inductor such as pseudoephedrine, ee's up to 28% have been obtained. The influence of zeolite on several chiral esters of 2-benzoyladamantane-2-carboxylic acids has also been examined. Whereas in solution the diastereomeric excess is 15%, in zeolite the δ-ketoesters are obtained in 79% de (best examples). Ab initio computations suggest that enhancement of chiral induction within zeolites is likely to be due to cation complexation with the reactant ketone. Alkali ion-organic interaction, a powerful tool, is waiting to be fully exploited in photochemical and thermal reactions. In this context zeolites could be a useful medium as one could view them as a reservoir of "naked" alkali ions that are only partially coordinated to the zeolite walls.