6833-18-7

Basic information

• Product Name: 4-METHYLBENZANILIDE
• Synonyms: P-TOLUANILIDE;P-METHYL BENZANILIDE;AKOS 244-40;4-TOLUANILIDE;4-METHYLBENZANILIDE;N-Phenyl-4-methylbenzamide;N-Phenyl-p-toluamide;BenzaMide, 4-Methyl-N-phenyl-
• CAS NO: 6833-18-7
• Molecular Formula: C₁₄H₁₃NO
• Molecular Weight: 211.26
• Product Categories: Aromatic Carboxylic Acids, Amides, Anilides, Anhydrides & Salts
• Mol File: 6833-18-7.mol
• Article Data: 189

Chemical Properties

• Melting Point: 183 °C
• Boiling Point: 277.716°C at 760 mmHg
• Flash Point: 163.142°C
• Appearance: /
• Density: 1.145g/cm³
• Vapor Pressure: 0.004mmHg at 25°C
• Refractive Index: 1.63
• PKA: 13.76±0.70(Predicted)
• CAS DataBase Reference: 4-METHYLBENZANILIDE(CAS DataBase Reference)
• NIST Chemistry Reference: 4-METHYLBENZANILIDE(6833-18-7)
• EPA Substance Registry System: 4-METHYLBENZANILIDE(6833-18-7)

Safety Data

• Hazardous Substances Data: 6833-18-7(Hazardous Substances Data)

Usage

InChI:InChI=1/C14H13NO/c1-11-7-9-12(10-8-11)14(16)15-13-5-3-2-4-6-13/h2-10H,1H3,(H,15,16)

Upstream product

• 79-37-8 oxalyl dichloride 
• 60-29-7 diethyl ether 
• 2998-92-7 (Z)-phenyl(p-tolyl)methanone oxime 
• 2998-91-6 p-tolyl phenyl ketoxime 
• 21443-49-2 3,4-bis(p-methylbenzoyl)-1,2,5-oxadiazole-N-oxide 
• 62-53-3 aniline 
• 104-87-0 4-methyl-benzaldehyde 
• 14338-21-7 tri-(4-methylphenyl)aluminum 
• 103-71-9 phenyl isocyanate 
• 108-88-3 toluene 
• 874-60-2 4-methyl-benzoyl chloride 
• 369-57-3 benzenediazonium tetrafluoroborate 
• 104-85-8 para-methylbenzonitrile 
• 1900-85-2 phenyl p-methylbenzoate 

Downstream Products

• 34916-13-7 N-(chloro(p-tolyl)methylene)benzenamine 
• 68587-15-5 (4-(dimethylamino)phenyl)(p-tolyl)methanone 
• 25110-49-0 4-methyl-N,N'-diphenyl-benzamidine 
• 5866-76-2 (4-Methyl-benzoyl)-phenyl-carbamic acid isopropyl ester 
• 20199-06-8 4-methylthiobenzanilide 
• 100990-65-6 4-methyl-N-(4-(4-methylbenzamido)phenyl)-N-phenylbenzamide 
• 40686-26-8 4-Methyl-N,N-diphenylbenzamide 
• 1027895-70-0 2-[Hydroxy-(3-methoxy-phenyl)-methyl]-4-methyl-N-phenyl-benzamide 
• 329969-90-6 [1-Benzotriazol-1-yl-1-p-tolyl-meth-(E)-ylidene]-phenyl-amine 
• 100-21-0 terephthalic acid 
• 34916-13-7 N-Phenyl-p-toluol-carboximidsaeure-chlorid 
• 161768-67-8 N-[(Z)-1H-1,2,3-benzotriazol-1-yl(4-methylphenyl)methylidene]aniline 
• 93-98-1 N-phenyl benzoyl amide 
• 5436-83-9 N-benzyl-4-methylbenzamide 

Relevant articles and documents

Water-Soluble Non-Classical Benzene Mimetics

A new generation of saturated benzene mimetics, 2-oxabicyclo[2.1.1]hexanes, was developed. These compounds were designed as analogues of bicyclo[1.1.1]pentane with an improved water solubility. Crystallographic analysis of 2-oxabicyclo[2.1.1]hexanes revea

Visible-Light Carbon Nitride-Catalyzed Aerobic Cyclization of Thiobenzanilides under Ambient Air Conditions

A metal-free heterogeneous photocatalysis has been developed for the synthesis of benzothiazoles via intramolecular C-H functionalization/C-S bond formation of thiobenzanilides by inexpensive graphitic carbon nitride (g-C3N4) under visible-light irradiation. This reaction provides access to a broad range of 2-substituted benzothiazoles in high yields under an air atmosphere at room temperature without addition of a strong base or organic oxidizing reagents. In addition, the catalyst was found to be stable and reusable after five reaction cycles.

Palladium-Catalyzed Desulfurative Hiyama Coupling of Thioureas to Achieve Amides via Selective C-N Bond Cleavage

Palladium-catalyzed Hiyama coupling of active thioureas via selective C-N bond cleavage is reported. Notably, the new approach employed active thioureas as coupling partners in the presence of arylsilanes to give amides in good yield. Further, this strategy, which utilized CuF 2as a key oxidant and activator, afforded various amide products under mild conditions and an easy to handle procedure without extra base.