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69180-59-2

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69180-59-2 Usage

Check Digit Verification of cas no

The CAS Registry Mumber 69180-59-2 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 6,9,1,8 and 0 respectively; the second part has 2 digits, 5 and 9 respectively.
Calculate Digit Verification of CAS Registry Number 69180-59:
(7*6)+(6*9)+(5*1)+(4*8)+(3*0)+(2*5)+(1*9)=152
152 % 10 = 2
So 69180-59-2 is a valid CAS Registry Number.

69180-59-2SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 12, 2017

Revision Date: Aug 12, 2017

1.Identification

1.1 GHS Product identifier

Product name 1-iodosyl-4-methylbenzene

1.2 Other means of identification

Product number -
Other names p-iodosyltoluene

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:69180-59-2 SDS

69180-59-2Relevant articles and documents

Synthesis of Diverse Aryliodine(III) Reagents by Anodic Oxidation?

Zu, Bing,Ke, Jie,Guo, Yonghong,He, Chuan

supporting information, p. 627 - 632 (2021/02/12)

An anodic oxidation enabled synthesis of hypervalent iodine(III) reagents from aryl iodides is demonstrated. Under mild electrochemical conditions, a range of aryliodine(III) reagents including iodosylarenes, (difunctionaliodo)arenes, benziodoxoles and diaryliodonium salts can be efficiently synthesized and derivatized in good to excellent yields with high selectivity. As only electrons serve as the oxidation reagents, this method offers a more straightforward and sustainable manner avoiding the use of expensive or hazardous chemical oxidants.

Photocatalytic Fluoro Sulfoximidations of Styrenes

Bolm, Carsten,Ma, Ding,Tu, Yongliang,Wang, Chenyang

supporting information, p. 14134 - 14137 (2020/06/17)

Reactions of difluoroiodotoluene with NH-sulfoximines provide new hypervalent iodine(III) reagents, which photocatalytically transfer a fluoro and a sulfoximidoyl group onto styrenes with high regioselectivity. The substrate scope is broad with respect to

SYNTHESIS OF HYPERVALENT IODINE REAGENTS WITH DIOXYGEN

-

Paragraph 0071-0072, (2019/01/15)

Methods of synthesis of hypervalent iodine reagents and methods for oxidation of organic compounds are disclosed.

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