69371-59-1Relevant articles and documents
Synthesis of Cyclic β-Silylalkenyl Triflates via an Alkenyl Cation Intermediate
Lee, Craig J.,Swain, Manisha,Kwon, Ohyun
, p. 5474 - 5477 (2018/09/13)
Trimethylsilylalkyne derivatives are transformed into cyclic β-silylalkenyl triflates through cationic cyclization and subsequent trapping of the alkenyl cation by a triflate anion. β-Silylcyclohexenyl triflates and 3-trimethylsilyl-1,4-dihydronaphth-2-yl
Cooperative Palladium/Proline-Catalyzed Direct α-Allylic Alkylation of Ketones with Alkynes
Yang, Chi,Zhang, Kaifan,Wu, Zijun,Yao, Hequan,Lin, Aijun
supporting information, p. 5332 - 5335 (2016/11/02)
The cooperative palladium/l-proline-catalyzed direct α-allylic alkylation of ketones with alkynes is achieved. This reaction exhibits high atom economy since a leaving group is not liberated and a stoichiometric amount of extra oxidant is not needed. A br
Pd(0)-catalyzed 1,1-diarylation of ethylene and allylic carbonates
Saini, Vaneet,Liao, Longyan,Wang, Qiaofeng,Jana, Ranjan,Sigman, Matthew S.
supporting information, p. 5008 - 5011 (2013/10/22)
An efficient protocol for the one-step synthesis of biologically relevant 1,1-diarylalkanes has been described. This reaction introduces two different aryl groups across the terminal end of simple feedstock alkenes such as ethylene and allylic carbonates.