6941-68-0

Basic information

• Product Name: prop-2-en-1-yl 4-methoxybenzoate
• Synonyms: Allyl 4-methoxybenzoate
• CAS NO: 6941-68-0
• Molecular Formula: C₁₁H₁₂O₃
• Molecular Weight: 192.2112
• Mol File: 6941-68-0.mol
• Article Data: 29

Chemical Properties

• Boiling Point: 289.6°C at 760 mmHg
• Flash Point: 117°C
• Density: 1.071g/cm³
• Vapor Pressure: 0.00218mmHg at 25°C
• Refractive Index: 1.51
• CAS DataBase Reference: prop-2-en-1-yl 4-methoxybenzoate(CAS DataBase Reference)
• NIST Chemistry Reference: prop-2-en-1-yl 4-methoxybenzoate(6941-68-0)
• EPA Substance Registry System: prop-2-en-1-yl 4-methoxybenzoate(6941-68-0)

Safety Data

• Hazardous Substances Data: 6941-68-0(Hazardous Substances Data)

Upstream product

• 100-07-2 4-methoxy-benzoyl chloride 
• 107-18-6 allyl alcohol 
• 24850-33-7 allyltributylstanane 
• 625-38-7 but-3-enoic acid 
• 52509-81-6 potassium 4-methoxybenzoate 
• 106-95-6 allyl bromide 
• 121-98-2 methyl 4-methoxybenzoate 
• 100-09-4 4-methoxybenzoic acid 
• 123-11-5 4-methoxy-benzaldehyde 
• 80735-94-0 1-Phenyl-3-buten-1-ol 
• 107-05-1 3-chloroprop-1-ene 
• 556-56-9 allyl iodid 
• 14271-83-1 4-methoxybenzoyl cyanide 
• 104-47-2 p-methoxybenzylnitrile 

Downstream Products

• 99859-52-6 4-methoxy-benzoic acid-(β,β'-dibromo-isopropyl ester) 
• 99859-53-7 4-methoxy-benzoic acid-(2,3-dibromo-propyl ester) 
• 100-09-4 4-methoxybenzoic acid 
• 422268-10-8 4-methoxy-benzoic acid 2-oxo-ethyl ester 
• 957146-89-3 (E)-4-methoxy-4-oxobut-2-en-1-yl 4-methoxybenzoate 
• 72164-71-7 (R)-2,3-dihydroxypropyl 4-methoxybenzoate 
• 123-38-6 propionaldehyde 
• 1372715-45-1 1-methoxy-1-oxo-2-phenylpent-4-en-2-yl 4-methoxybenzoate 
• 1384266-28-7 (Z)-prop-1-enyl 4-methoxybenzoate 
• 1384266-27-6 (E)-prop-1-enyl 4-methoxybenzoate 
• 1236063-60-7 2-bromoallyl 4-methoxybenzoate 
• 1338089-99-8 C₁₁H₁₁BrO₃ 
• 1445674-65-6 3-(tetrahydrofuran-2-yl)propyl 4-methoxybenzoate 
• 1445674-68-9 4-hydroxy-4-methylpentyl 4-methoxybenzoate 

Relevant articles and documents

Electron donor-acceptor (EDA)-complex enabled SF5Cl addition on alkenes and alkynes

A new method for the addition of SF5Cl on unsaturated compounds was developed, based on the use of an electron donor-acceptor (EDA)-complex and visible light irradiation. The reaction does not require the presence of oxygen to proceed, compared

Enantioselective Three-Component Fluoroalkylarylation of Unactivated Olefins through Nickel-Catalyzed Cross-Electrophile Coupling

A nickel-catalyzed, enantioselective, three-component fluoroalkylarylation of unactivated alkenes with aryl halides and perfluoroalkyl iodides has been described. This cross-electrophile coupling protocol utilizes a chiral nickel/BiOx system as well as a pendant chelating group to facilitate the challenging three-component, asymmetric difunctionalization of unactivated alkenes, providing direct access to valuable chiral β-fluoroalkyl arylalkanes with high efficiency and excellent enantioselectivity. The mild conditions allow for a broad substrate scope as well as good functional group toleration.

Cobalt bis(acetylacetonate)–tert-butyl hydroperoxide–triethyl-silane: A general reagent combination for the Markovnikov-selective hydrofunctionalization of alkenes by hydrogen atom transfer

We show that cobalt bis(acetylacetonate) [Co(acac)2], tert-butyl hydroperoxide (TBHP), and triethylsilane (Et3SiH) constitute an inexpensive, general, and practical reagent combination to initiate a broad range of Markovnikov-selective alkene hydrofunctionalization reactions. These transformations are believed to proceed by cobalt-mediated hydrogen atom transfer (HAT) to the alkene substrate, followed by interception of the resulting alkyl radical intermediate with a SOMOphile. In addition, we report the first reductive couplings of unactivated alkenes and aryldiazonium salts by an HAT pathway. The simplicity and generality of the Co(acac)2–TBHP–Et3SiH reagent combination suggests it as a useful starting point to develop HAT reactions in complex settings.