69642-11-1

Basic information

• Product Name: cis-1,2-bis(perfluorophenyl)diazene
• Synonyms: cis-1,2-bis(perfluorophenyl)diazene
• CAS NO: 69642-11-1
• Molecular Weight: 362.129
• Mol File: 69642-11-1.mol
• Article Data: 5

Chemical Properties

• CAS DataBase Reference: cis-1,2-bis(perfluorophenyl)diazene(CAS DataBase Reference)
• NIST Chemistry Reference: cis-1,2-bis(perfluorophenyl)diazene(69642-11-1)
• EPA Substance Registry System: cis-1,2-bis(perfluorophenyl)diazene(69642-11-1)

Safety Data

• Hazardous Substances Data: 69642-11-1(Hazardous Substances Data)

Upstream product

• 1423-15-0 perfluorophenyl azide 
• 108-88-3 toluene 
• 36375-78-7 pentafluorophenyl nitrene 
• 2285-06-5 (E)-1,2-bis(pentafluorophenyl)diazene 
• 771-60-8 2,3,4,5,6-pentafluoroaniline 

Downstream Products

• 2285-06-5 (E)-1,2-bis(pentafluorophenyl)diazene 

Relevant articles and documents

Switching the Spin State of Pentafluorophenylnitrene: Isolation of a Singlet Arylnitrene Complex

The chemistry of arylnitrenes is dominated by their triplet ground states and excited open-shell singlet states. This results in radical-type reactions and unwanted rearrangements, which diminish the use of arylnitrenes as intermediates in organic synthes

Azo?phenyl stacking: A persistent self-assembly motif guides the assembly of fluorinated cis-azobenzenes into photo-mechanical needle crystals

We describe a novel, persistent motif of molecular assembly in photo-mechanical crystals and cocrystals of fluorinated cis-azobenzenes. The azo?phenyl stacking, preserved upon either chemical substitution or halogen-bonded cocrystallization, guides the assembly of fluorinated cis-azobenzenes into columnar stacks and drives the formation of crystals with needle-like morphologies optimal for photo-mechanical motion.

High Yields of Formal CH Insertion Products in the Reactions of Polyfluorinated Aromatic Nitrenes

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