69746-44-7

Basic information

• Product Name: Ethanethioic acid, S-(3-methoxyphenyl) ester
• CAS NO: 69746-44-7
• Molecular Formula: C9H10O2S
• Molecular Weight: 182.243
• Mol File: 69746-44-7.mol
• Article Data: 6

Chemical Properties

• CAS DataBase Reference: Ethanethioic acid, S-(3-methoxyphenyl) ester(CAS DataBase Reference)
• NIST Chemistry Reference: Ethanethioic acid, S-(3-methoxyphenyl) ester(69746-44-7)
• EPA Substance Registry System: Ethanethioic acid, S-(3-methoxyphenyl) ester(69746-44-7)

Safety Data

• Hazardous Substances Data: 69746-44-7(Hazardous Substances Data)

Upstream product

• 766-85-8 3-methoxy-1-iodobenzene 
• 10387-40-3 potassium thioacetate 
• 15570-12-4 3-methoxybenzenethiol 
• 108-24-7 acetic anhydride 
• 108-22-5 Isopropenyl acetate 
• 217813-03-1 3-methoxy-2-(trimethylsilyl)phenyl-trifluoromethanesulfonate 
• 75-36-5 acetyl chloride 

Relevant articles and documents

Magnetically recyclable silica-coated ferrite magnetite-K10montmorillonite nanocatalyst and its applications in O, N, and S-acylation reaction under solvent-free conditions

Novel silica-coated ferrite nanoparticles supported with montmorillonite (K10) have been prepared successfully by using a simple impregnation method. Further, these nanoparticles were characterized by using different analytical methods like FT-IR, PXRD, EDS, and FE-SEM techniques. In addition, these nanoparticles have been explored for their catalytic activity for the O, N, and S-acylation reactions under solvent-free conditions which gave moderate to excellent yields in a much shorter reaction time. Moreover, these nanoparticles could easily be separated out from the reaction medium after the reaction completion by using an external magnetic field and have been re-used for 10 cycles without any significant loss of the catalytic activity.

Thioesters as Bifunctional Reagents for 2-Naphthylamine Sulfuracylation

An efficient and convenient strategy for the preparation of diaryl sulfides via a Fe-promoted direct sulfuracylation of 2-naphthylamine using thioesters as bifunctional reagents is described. This synthetic strategy features high chemoselectivity, good substrate scope and functional group tolerance. (Figure presented.).

S-Acetylation of Thiols Mediated by Triflic Acid: A Novel Route to Thioesters

This paper demonstrates an efficient, mild, and chemoselective synthesis of various thioesters via a HOTf-catalyzed S-acetylation of aromatic and aliphatic thiols using isopropenyl acetate as a cheap and convenient acetylating agent. During our tests, we also investigated the differences between the activities of metal triflates and triflic acid as catalysts in the acetylation of thiols. Finally, the potential of our concept has been increased by the implementation of Nafion as a heterogeneous catalyst for S-acetylation of thiols.