7029-30-3Relevant articles and documents
Remarkably Selective Formation of Allenyl and Dienyl Alcohols via Ni-Catalyzed Coupling Reaction of Conjugated Enyne, Aldehyde, and Organozinc Reagents
Mori, Yasuyuki,Kawabata, Toshiki,Onodera, Gen,Kimura, Masanari
supporting information, p. 2385 - 2395 (2016/07/27)
A nickel catalyst promotes the multi-component reactions (MCRs) of conjugated enynes, aldehydes, and organozinc reagents to form unsaturated alcohols. Ligand effects dramatically control the regioselectivity in these Ni-catalyzed MCRs, leading to the selective formation of allenyl alcohols and conjugated dienyl alcohols.
Nickel-catalyzed multicomponent coupling of alkyne, buta-1,3-diene, and dimethylzinc under carbon dioxide
Mori, Yasuyuki,Mori, Takamichi,Onodera, Gen,Kimura, Masanari
supporting information, p. 2287 - 2292 (2014/11/26)
A nickel catalyst promoted the coupling of alkynes with buta-1,3-diene and dimethylzinc under carbon dioxide to provide (5E,8Z)-2-vinyldeca-5,8-dienoic acids with high regio- and stereo selectivity. Georg Thieme Verlag Stuttgart. New York.
Copper-Catalyzed Electrophilic Amination of Diorganozinc Reagents
Berman, Ashley M.,Johnson, Jeffrey S.
, p. 5680 - 5681 (2007/10/03)
The copper-catalyzed electrophilic amination of diorganozinc reagents employing O-acyl N,N-dialkyl hydroxylamine derivatives as aminating agents is described. This reaction offers a general method for the preparation of tertiary amines in high yields and is noteworthy for its convenience both in terms of reaction conditions employed (room temperature, ≤1 h) and ease of product isolation (acid/base extractive workup). Copyright