7091-12-5

Basic information

• Product Name: 2-Propyloxybenzaldehyde
• Synonyms: ASISCHEM V34141;2-PROPYLOXYBENZALDEHYDE;TIMTEC-BB SBB001592;o-Propoxybenzaldehyde;2-propoxybenzaldehyde(SALTDATA: FREE);2-n-Propoxybenzaldehyde, 97+%;BAS 09975368;Benzaldehyde,-2-propoxy
• CAS NO: 7091-12-5
• Molecular Formula: C₁₀H₁₂O₂
• Molecular Weight: 164.2
• Product Categories: Benzaldehyde
• Mol File: 7091-12-5.mol
• Article Data: 14

Chemical Properties

• Melting Point: 173-174 °C
• Boiling Point: 264.6°Cat760mmHg
• Flash Point: 113.2°C
• Appearance: /
• Density: 1.038g/cm³
• Vapor Pressure: 0.00963mmHg at 25°C
• Refractive Index: 1.531
• Sensitive: Air Sensitive
• CAS DataBase Reference: 2-Propyloxybenzaldehyde(CAS DataBase Reference)
• NIST Chemistry Reference: 2-Propyloxybenzaldehyde(7091-12-5)
• EPA Substance Registry System: 2-Propyloxybenzaldehyde(7091-12-5)

Safety Data

• Hazard Codes: Xi
• HazardClass: IRRITANT
• Hazardous Substances Data: 7091-12-5(Hazardous Substances Data)

Usage

General Description

2-Propyloxybenzaldehyde is a chemical compound with the molecular formula C11H14O2. It is also known by other names such as Benzenecarbonal, 2-(Propyloxy) and Phenyl propyl ether. It is categorized under aromatic aldehydes, a group of organic compounds consisting of an alkyl group attached to a formyl group. It is generally in a solid state and has a pale yellow color. Although there is limited data available on its properties, it is generally used in the production of other chemicals or as a synthetic intermediate in various chemical reactions. The risk or safety factors associated are still not fully known and it should be handled with appropriate protective measures.

InChI:InChI=1/C10H12O2/c1-2-7-12-10-6-4-3-5-9(10)8-11/h3-6,8H,2,7H2,1H3

Upstream product

• 90-02-8 salicylaldehyde 
• 107-08-4 1-iodo-propane 
• 17954-11-9 2-(3-bromopropyloxy)benzaldehyde 
• 28752-82-1 2-(allyloxy)benzaldehyde 
• 89-95-2 2-methyl-benzyl alcohol 
• 5747-23-9 2-phenyl-1,3,2-benzodioxaborole 

Downstream Products

• 108565-14-6 (2-propoxy-phenyl)-acetone 
• 110534-55-9 2-propoxy-benzaldehyde-selenosemicarbazone 
• 99987-60-7 2-propoxy-benzaldehyde-semicarbazone 
• 7420-46-4 2-propoxy-benzaldehyde-thiosemicarbazone 
• 508168-57-8 6-(2-propoxybenzylamino)hexanoic acid methyl-(8-{methyl[6-(2-propoxybenzylamino)hexanoyl]amino}octyl)amide 
• 508168-34-1 6-[ethyl-(2-propoxy-benzyl)-amino]-hexanoic acid [8-({6-[ethyl-(2-propoxy-benzyl)-amino]-hexanoyl}-methyl-amino)-octyl]-methyl-amide 
• 112562-35-3 2-(2-Propoxy-phenyl)-thiazolidine-3-carbothioic acid methylamide 
• 6280-96-2 2-propoxyphenol 
• 729594-50-7 N-(5,8-dimethyl-5H-1,2,4-triazino[5,6-b]indol-3-yl)-N'-[1-(2-propoxy-phenyl)-methylidene]-hydrazine 
• 729594-51-8 N-(8-methoxy-5-methyl-5H-1,2,4-triazino[5,6-b]indol-3-yl)-N'-[1-(2-propoxy-phenyl)-methylidene]-hydrazine 

Relevant articles and documents

Different structures of the two peroxisome proliferator-activated receptor gamma (PPARγ) ligand-binding domains in homodimeric complex with partial agonist, but not full agonist

We designed and synthesized acylsulfonamide derivative (3) as a human peroxisome proliferator-activated receptor gamma (hPPARγ) partial agonist by structural modification of hPPARγ full agonist 1. Co-crystallization of 3 with hPPARγ LBD afforded a homodim

Enhanced Reactivity of Aerobic Diimide Olefin Hydrogenation with Arylboronic Compounds: An Efficient One-Pot Reduction/Oxidation Protocol

A catalyst-free and efficient method for simultaneous olefin hydrogenation and oxidation of arylboronate esters to phenols with hydrazine hydrate and molecular oxygen is presented. The process is based on the utilization of a readily available Lewis acidic arylboron compound, which evades common problems associated with the catalyst-free aerobic hydrogenation of olefins with diimide. Using an operationally simple procedure, the protocol smoothly delivers phenol derivatives and various alkanes in excellent yields with remarkable functional group compatibility. The method allows the reaction to be scaled up to 1 g of the starting materials.

Chemoselective hydrogenation method catalyzed by Pd/C using diphenylsulfide as a reasonable catalyst poison

While Pd/C is one of the most useful catalysts for hydrogenation, the high catalyst activity of Pd/C causes difficulty in its application to chemoselective hydrogenation between different types of reducible functionalities. In order to achieve chemoselective hydrogenation using Pd/C, we investigated catalyst poison as a controller of the catalyst activity. We found that the addition of Ph2S (diphenylsulfide) to the Pd/C-catalyzed hydrogenation reaction mixture led to reasonable deactivation of Pd/C. By the use of the Pd/C-Ph2S catalytic system, olefins, acetylenes, and azides can be selectively reduced in the coexistence of aromatic carbonyls, aromatic halides, cyano groups, benzyl esters, and N-Cbz (benzyloxycarbonyl) protecting groups. The present method is promising as a general and practical chemoselective hydrogenation process in synthetic organic chemistry.