70935-14-7Relevant articles and documents
Synthesis of α-keto aldehydes via selective Cu(i)-catalyzed oxidation of α-hydroxy ketones
Zheng, Shasha,Smit, Wietse,Spannenberg, Anke,Tin, Sergey,de Vries, Johannes G.
, p. 4639 - 4642 (2022/04/19)
An efficient approach to synthesize α-keto aldehydes was established through selective oxidation of α-hydroxy ketones catalyzed by Cu(i) using oxygen as oxidant. A wide array of α-keto aldehydes was prepared with isolated yields of up to 87%. The potential utilization of this reaction was evaluated by gram-scale reactions and synthetic applications.
Kinetics and mechanism of oxidation of o-, m- and p-hydroxy-acetophenones by hexacyanoferrate(III) in alkaline medium
Gupta, K. C.,Gupta, Renu,Saxena, Usha
, p. 253 - 254 (2007/10/02)
Oxidation of o-, p- and m-hydroxyacetophenones by hexacyanoferrate(III) in alkaline medium is first order each in and .Added KCl and increase in increase the rate.Activation parameters have been calculated and