71031-04-4

Basic information

• Product Name: (2S)-2-[(4-METHOXYPHENOXY)METHYL]OXIRANE
• Synonyms: (S)-4-METHOXYPHENYL GLYCIDYL ETHER;(2S)-2-[(4-METHOXYPHENOXY)METHYL]OXIRANE
• CAS NO: 71031-04-4
• Molecular Formula: C₁₀H₁₂O₃
• Molecular Weight: 180.2
• Mol File: 71031-04-4.mol
• Article Data: 28

Chemical Properties

• Appearance: /
• CAS DataBase Reference: (2S)-2-[(4-METHOXYPHENOXY)METHYL]OXIRANE(CAS DataBase Reference)
• NIST Chemistry Reference: (2S)-2-[(4-METHOXYPHENOXY)METHYL]OXIRANE(71031-04-4)
• EPA Substance Registry System: (2S)-2-[(4-METHOXYPHENOXY)METHYL]OXIRANE(71031-04-4)

Safety Data

• Hazardous Substances Data: 71031-04-4(Hazardous Substances Data)

Usage

General Description

The chemical compound (2S)-2-[(4-METHOXYPHENOXY)METHYL]OXIRANE is an epoxide molecule with a methoxyphenoxy side chain. It is a chiral compound, with the (2S) configuration indicating that it has a specific spatial arrangement of atoms. (2S)-2-[(4-METHOXYPHENOXY)METHYL]OXIRANE has potential applications in organic synthesis, as epoxides are versatile intermediates in the production of various chemical products. The methoxyphenoxy side chain may also impart specific properties or functions to the molecule, depending on the context in which it is used. Overall, (2S)-2-[(4-METHOXYPHENOXY)METHYL]OXIRANE is a compound with interesting structural and potentially useful chemical properties.

Upstream product

• 13391-35-0 allyl (4-methoxyphenyl) ether 
• 130998-34-4 Benzoic acid (R)-1-bromomethyl-2-(4-methoxy-phenoxy)-ethyl ester 
• 142037-06-7 (R)-1-Chloro-3-(4-methoxy-phenoxy)-propan-2-ol 
• 17131-52-1 (S)-1-O-(4-methoxyphenyl)glycerol 
• 204443-54-9 Toluene-4-sulfonic acid (R)-2-hydroxy-3-(4-methoxy-phenoxy)-propyl ester 
• 70987-78-9 (S)-Glycidyl tosylate 
• 150-76-5 4-methoxy-phenol 
• 115314-14-2 (2s)-(+)-glycidyl 3-nitrobenzenesulfonate 
• 2211-94-1 2,3-epoxypropyl p-methoxyphenyl ether 
• 25772-85-4 (+/-)-1-chloro-3-(4-methoxyphenyloxy)-2-propanol 
• 130998-32-2 (R)-1,2-O-isopropylidene-3-O-(4-methoxyphenyl)glycerol 
• 130998-37-7 Acetic acid (R)-1-acetoxymethyl-2-(4-methoxy-phenoxy)-ethyl ester 
• 130998-36-6 Methanesulfonic acid (S)-2-methanesulfonyloxy-1-(4-methoxy-phenoxymethyl)-ethyl ester 
• 17131-52-1 (R)-3-(p-methoxyphenoxy)-1,2-propanediol 

Downstream Products

• 156737-65-4 1-O-hexadecyl-3-O-(p-methoxyphenyl)-sn-glycerol 
• 204443-56-1 4'-methoxyphenyl (S)-2-hydroxy-4-octadecynyl ether 
• 131760-56-0 (R)-3-azido-1-O-(4'-methoxyphenyl)-1,2-propanediol 
• 131760-55-9 (2S)-1-azido-3-(4-methoxyphenoxy)propan-2-ol 
• 796843-99-7 (R)-1-(4-Methoxy-phenoxy)-hex-5-en-2-ol 
• 351026-61-4 (R)-1-(4-Methoxy-phenoxy)-pent-4-en-2-ol 
• 391901-51-2 (2 S)-1-[(4-Aminophenethyl)amino]-3-(4-methoxyphenoxy)-2-propanol 
• 17131-52-1 (S)-1-O-(4-methoxyphenyl)glycerol 
• 895153-36-3 (S)-1-(4-Methoxy-phenoxy)-5-trimethylsilanyl-pent-4-yn-2-ol 
• 927385-42-0 (R)-1-(4-methoxyphenoxy)-5-phenylpent-4-yn-2-ol 
• 927385-47-5 (R)-1-methoxy-4-[5-phenyl-2-(prop-2-ynyloxy)pent-4-ynyloxy]benzene 
• 927385-59-9 (R)-3-[N-4-[1-(4-methoxyphenoxy)-5-phenylpent-4-yn-2-yloxy]but-2-ynyl-N-(2-phenoxyethyl)amino]propanenitrile 
• 858345-18-3 2,3-di-O-palmitoyl-1-O-(4'-methoxyphenyl)-sn-glycerol 

Relevant articles and documents

Engineering a homochiral metal-organic framework based on an amino acid for enantioselective separation

A chiral metal-organic framework possessing an open amphiphilic channel is constructed from a dicarboxylate ligand derived from an amino acid and is shown to be an efficient and recyclable chiral solid adsorbent, which is capable of separating racemic secondary alcohols, epoxides, and ibuprofen with very high enantioselectivity.

Chiral Bifunctional Metalloporphyrin Catalysts for Kinetic Resolution of Epoxides with Carbon Dioxide

Chiral binaphthyl-strapped Zn(II) porphyrins with triazolium halide units were synthesized as bifunctional catalysts for kinetic resolution of epoxides with CO2. Several catalysts were screened by changing the linker length and nucleophilic counteranions, and the optimized catalyst accelerated the enantioselective reaction at ambient temperature to produce optically active cyclic carbonates and epoxides.

Chiral Macrocyclic Organocatalysts for Kinetic Resolution of Disubstituted Epoxides with Carbon Dioxide

Among chiral macrocycles 1 synthesized, 1m with the 3,5-bis(trifluoromethyl)phenylethynyl group was the best organocatalyst for the enantioselective synthesis of cyclic carbonates from disubstituted or monosubstituted epoxides and CO2. The X-ray crystal structure of 1m revealed a well-defined chiral cavity with multiple hydrogen-bonding sites that is suitable for the enantioselective activation of epoxides. A catalytic cycle proposed was supported by DFT calculations.