711-91-1

Basic information

• Product Name: 4-Oxo-4-(2'-oxocyclohexyl)butansaeure
• CAS NO: 711-91-1
• Molecular Weight: 198.219
• Mol File: 711-91-1.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 4-Oxo-4-(2'-oxocyclohexyl)butansaeure(CAS DataBase Reference)
• NIST Chemistry Reference: 4-Oxo-4-(2'-oxocyclohexyl)butansaeure(711-91-1)
• EPA Substance Registry System: 4-Oxo-4-(2'-oxocyclohexyl)butansaeure(711-91-1)

Safety Data

• Hazardous Substances Data: 711-91-1(Hazardous Substances Data)

Upstream product

• 670-80-4 4-cyclohexen-1-ylmorpholine 
• 543-20-4 succinoyl dichloride 
• 114212-45-2 4-oxo-5-decenedioic acid 
• 114212-43-0 (E)-4,5-Dihydro-5-(2'-oxocylohexyliden)furan-2(3H)-on 
• 7732-18-5 water 

Relevant articles and documents

179. Die Oxidation von 3-(1-Nitro-2-oxocycloalkyl)propanal

Oxidation of the title compound 1 with KMnO4 under neutral condiitons led to the corresponding acid 2, 5-(2,3,4,5-tetrahydro-2-nitro-5-oxo-2-furyl)pentanoic acid (4), and 4-oxononadioic acid (6).On the basis of experimental results the mechanism of the formation of 4 is discussed (Scheme 1).Oxidation of 1 with KMnO4 under basic conditions gave 6 which was transformed to (E)-4,5-dihydro-5-(2'-oxocyclopentyliden)furan-2(3H)-one (12) with benzene/TsOH (Scheme 3).In contrast to this result the corresponding 4-oxoheptandioic acid (22) yields 1,6-dioxaspirononan-2,7-dione (23) only (Scheme 4).