7124-50-7Relevant articles and documents
Xanthates as Thiol Surrogates for Nucleophilic Substitution with Aryl Halides
Sokolov, Anatolii I.,Mikhaylov, Andrey A.,Baleeva, Nadezhda S.,Baranov, Mikhail S.
, p. 4350 - 4357 (2021/08/24)
We herein report an unprecedented xanthate-based protocol for the preparation of aryl-alkyl thioethers. Heating xanthates with aryl halides and namely cesium carbonate in methanol provides the target thioethers in generally good yields within short reaction times. This method allows one to avoid contact with odorous thiols and also to introduce substituents of which the corresponding thiols are virtually unavailable or inconvenient in use.
Alkyl xanthic sour alkene propyl ester compound of preparation method (by machine translation)
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Paragraph 0020; 0021, (2017/03/17)
The invention discloses a alkyl xanthic sour alkene propyl ester compound of preparation method. A alkyl xanthic sour alkene propyl ester compound of preparation method, used for preparing alkyl xanthogen ally propyl ester dressing agent. Characterized in that a safe, non-corrosive to the allylic alcohol compound alternative flammable, extremely volatile allyl chlorine apperception compound as raw material, with the alkyl xanthic acid salt reaction for preparing alkyl xanthogen ally propyl ester compounds, through the liquid, washing, and drying to obtain alkyl xanthic sour alkene terephthalate, thus make the production process more environmental protection, security. (by machine translation)
Facile Syntheses of 1,3-Dithiol-2-ones and 1,3-Dithiole-2-thiones
Haley, Neil F.,Fichtner, Michael W.
, p. 2959 - 2962 (2007/10/02)
A facile ring closure of allyl xanthates or trithiocarbonates with iodine is discussed.The products of the reaction undergo basic dehydroiodination and acidic isomerization to give 1,3-dithiol-2-ones and -2-thiones in high yield.
