7152-42-3

Basic information

• Product Name: 10-Phenyl-10H-phenothiazine
• Synonyms: 10-Phenyl-10H-phenothiazine;10-Phenylphenothiazine
• CAS NO: 7152-42-3
• Molecular Formula: C₁₈H₁₃NS
• Molecular Weight: 275.37
• Mol File: 7152-42-3.mol
• Article Data: 53

Chemical Properties

• Melting Point: 94 °C
• Boiling Point: 411.2°C at 760 mmHg
• Flash Point: 202.5°C
• Appearance: /
• Density: 1.247g/cm³
• Vapor Pressure: 5.67E-07mmHg at 25°C
• Refractive Index: 1.7
• Storage Temp.: Keep in dark place,Sealed in dry,Room Temperature
• Solubility: soluble in Acetone
• PKA: -3.48±0.20(Predicted)
• CAS DataBase Reference: 10-Phenyl-10H-phenothiazine(CAS DataBase Reference)
• NIST Chemistry Reference: 10-Phenyl-10H-phenothiazine(7152-42-3)
• EPA Substance Registry System: 10-Phenyl-10H-phenothiazine(7152-42-3)

Safety Data

• Hazardous Substances Data: 7152-42-3(Hazardous Substances Data)

Usage

Description

10-Phenyl-10H-phenothiazine is a heterocyclic organic compound with a phenothiazine core and a phenyl group attached at the 10th position. It is characterized by its unique chemical structure and properties, making it a versatile molecule for various applications.

Uses

Used in Organic Synthesis:
10-Phenyl-10H-phenothiazine is used as an organic photo-catalyst for the synthesis of small molecules and polymerization reactions. Its photo-catalytic properties enable efficient and selective transformations under light irradiation, making it a valuable tool in organic chemistry.
Used in Pharmaceutical Industry:
10-Phenyl-10H-phenothiazine is used as a pharmaceutical intermediate for the synthesis of various drugs, including antidepressants, antipsychotics, and antimalarial agents. Its unique chemical structure allows for the development of new therapeutic agents with improved efficacy and reduced side effects.
Used in Dye-sensitized Solar Cells:
10-Phenyl-10H-phenothiazine is used as a dye in dye-sensitized solar cells (DSSCs) due to its strong light absorption and charge transfer properties. Its incorporation into DSSCs can enhance the overall efficiency and performance of these solar energy conversion devices.
Used in Analytical Chemistry:
10-Phenyl-10H-phenothiazine is used as a reagent in analytical chemistry for the detection and quantification of various metal ions and other analytes. Its selective binding properties and fluorescence characteristics make it a useful tool for sensitive and selective assays.
Used in Materials Science:
10-Phenyl-10H-phenothiazine is used in the development of new materials with unique properties, such as organic semiconductors, conductive polymers, and light-emitting materials. Its versatile chemical structure allows for the design and synthesis of novel materials with tailored properties for specific applications.

InChI:InChI=1/C18H13NS/c1-2-8-14(9-3-1)19-15-10-4-6-12-17(15)20-18-13-7-5-11-16(18)19/h1-13H

Upstream product

• 92-84-2 10H-phenothiazine 
• 591-50-4 iodobenzene 
• 98546-66-8 2-ethanesulfonylmethyl-5-bromo-thiophene 
• 52156-15-7 10-phenylphenothiazinium perchlorate 
• 637-88-7 1,4-Cyclohexanedione 
• 108-86-1 bromobenzene 
• 12775-96-1 copper 
• 583-55-1 1-Bromo-2-iodobenzene 
• 6320-02-1 o-bromothiophenol 
• 62-53-3 aniline 
• 108-90-7 chlorobenzene 
• 21848-84-0 1-bromo-2-[(2-bromophenyl)thio]benzene 
• 66003-78-9 triphenylsulfonium trifluoromethanesulfonate 
• 98-80-6 phenylboronic acid 

Downstream Products

• 23099-78-7 10-phenyl-10H-phenothiazine S-oxide 
• 107522-66-7 10-phenyl-phenothiazine-5,5-dioxide 
• 55267-55-5 10-phenyl-5-propylimino-5,10-dihydro-5λ⁴-phenothiazine 
• 55222-74-7 5-cyclohexylimino-10-phenyl-5,10-dihydro-5λ⁴-phenothiazine 
• 55222-72-5 5-ethylimino-10-phenyl-5,10-dihydro-5λ⁴-phenothiazine 
• 55222-70-3 5-methylimino-10-phenyl-5,10-dihydro-5λ⁴-phenothiazine 
• 55223-14-8 5-benzylimino-10-phenyl-5,10-dihydro-5λ⁴-phenothiazine 
• 56301-52-1 10-phenyl-10H-phenothiazine radical cation 
• 89922-57-6 3-bromo-10-phenylphenothiazine 
• 89922-58-7 3,7-dibromo-10-phenyl-10H-phenothiazine 
• 89922-59-8 3,7-dibromo-10-(4-bromophenyl)-10H-phenothiazine 
• 63524-03-8 10-(4 -bromophenyl)-10H-phenothiazine 

Relevant articles and documents

Effective suppression of interfacial charge recombination by a 12-crown-4 substituent on a double-anchored organic sensitizer and rotating disk electrochemical evidence

Mono/double-anchored phenothiazine-based dyes (DCE1-DCE4) containing various N-substituents (12-crown-4-substituted phenyl, 4-hexoxyphenyl, and bare phenyl) were synthesized and applied as sensitizers for dye-sensitized solar cells (DSSCs). The incorporat

Photoredox Catalytic Activation of Sulfur Hexafluoride for Pentafluorosulfanylation of α-Methyl- and α-Phenyl Styrene

Sulfur hexafluoride is inert, non-toxic, and cannot simply be applied as pentafluorosulfanylation reagent. We present the first photoredox catalytic way to convert it into pentafluorosulfanylated α-methyl and α-phenyl styrenes simply by using light. The work tackles the challenges of precise activation of sulfur hexafluoride by a photoredox catalyst with designed consecutive electron transfer cycles in a fashion that styrenes trap the generated pentafluorosulfanyl radical. The method overcomes the highly problematic access to vinylic and allylic pentafluorosulfanyl styrenes and combines it with the disposal of the most potent greenhouse gas. Together with the use of light as energy source, an exceptionally high level of sustainability is gained.

Photoredox Catalytic α-Alkoxypentafluorosulfanylation of α-Methyl- and α-Phenylstyrene Using SF6

SF6 was applied as pentafluorosulfanylation reagent to prepare ethers with a vicinal SF5 substituent through a one-step method involving photoredox catalysis. This method shows a broad substrate scope with respect to applicable alcoh

Unveiling Potent Photooxidation Behavior of Catalytic Photoreductants

We describe a photocatalytic system that reveals latent photooxidant behavior from one of the most reducing conventional photoredox catalysts, N-phenylphenothiazine (PTH). This aerobic photochemical reaction engages difficult to oxidize feedstocks, such as benzene, in C(sp2)-N coupling reactions through direct oxidation. Mechanistic studies are consistent with activation of PTH via photooxidation and with Lewis acid cocatalysts scavenging inhibitors inextricably formed in this process.

Photoactivated novel organic small-molecular matrixes and preparation method thereof, and application of photoactivated novel organic small-molecular matrixes in MALDI mass spectrometric detection

The invention provides photoactivated novel organic small-molecular matrixes and a preparation method thereof, and application of the photoactivated novel organic small-molecular matrixes in MALDI mass spectrometric detection. According to the invention,

Organic room-temperature phosphorescent material as well as preparation method and application thereof

The invention discloses an organic room-temperature phosphorescent material as well as a preparation method and application thereof. The structure of the phosphorescent material is shown as a formula(I), a formula (II) or a formula (III). The molecules all contain one or more phenothiazine units, and when the molecules are dispersed and immobilized in a rigid matrix PMMA, the material doped withthe molecules can be induced to generate room-temperature phosphorescence under the excitation of an ultraviolet lamp. Phenothiazine derivative molecules promote oxygen molecules in a matrix materialto be converted into singlet oxygen in the light induction process, and after the oxygen molecules are greatly consumed, the phenothiazine derivative molecules emit phosphorescence due to the fact that non-radiative energy dissipation is inhibited by a rigid environment provided by the matrix. The activated material can be inactivated again by heating or standing for a long time, and the process can be carried out repeatedly. The molecules in the invention can realize light-induced information writing and erasing in a transparent polymer matrix material, material support is provided for organic light information storage, reading and writing, and the practicability is extremely high.