72235-68-8

Basic information

• Product Name: 1,1,1,3,3,3-hexadeuterio-2-phenyl-2-propanol
• Synonyms: 1,1,1,3,3,3-hexadeuterio-2-phenyl-2-propanol
• CAS NO: 72235-68-8
• Molecular Weight: 142.146
• Mol File: 72235-68-8.mol
• Article Data: 8

Chemical Properties

• CAS DataBase Reference: 1,1,1,3,3,3-hexadeuterio-2-phenyl-2-propanol(CAS DataBase Reference)
• NIST Chemistry Reference: 1,1,1,3,3,3-hexadeuterio-2-phenyl-2-propanol(72235-68-8)
• EPA Substance Registry System: 1,1,1,3,3,3-hexadeuterio-2-phenyl-2-propanol(72235-68-8)

Safety Data

• Hazardous Substances Data: 72235-68-8(Hazardous Substances Data)

Upstream product

• 77956-17-3 1,2-diphenyl-2-trideuteriomethyl-3,3,3-trideuterio-1-propanone 
• 666-52-4 [⁽²⁾H₆]acetone 
• 591-51-5 phenyllithium 
• 108-86-1 bromobenzene 

Downstream Products

• 113305-58-1 (2-(4-(1,1,1,3,3,3-hexadeutero-2-propyl)phenylthio)-4-fluorophenyl)acetic acid 
• 113305-72-9 4-(1,1,1,3,3,3-hexadeutero-2-propyl)benzenesulphonyl chloride 
• 113305-57-0 4-(1,1,1,3,3,3-hexadeutero-2-propyl)thiophenol 
• 75296-07-0 C₉H₅⁽²⁾H₆⁽¹⁺⁾ 
• 10378-58-2 1,1,3,3,3-pentadeuterio-2-phenylpropene 
• 53102-26-4 2-Chloro-2-phenyl-1,1,1,3,3,3-hexadeuteropropane 
• 20201-29-0 2-phenyl<1,1,1,3,3,3-2H6>propane 

Relevant articles and documents

Kinetics of hydrogen atom transfer from (η5-C 5H5)Cr(CO)3H to various olefins: Influence of olefin structure

Treating (η5-C5H5)Cr(CO)3H (1) or (η5-C5H5)Cr(CO)3D (1-d1) with an excess of olefin containing the opposite isotope generally leads to H/D exchange, althoug

Unusual Fragmentation of 1,1,2,2,3,3-Hexamethylindan. Methyl Group Equilibration and Multi-step Skeletal Rearrangements in the (1+) Ions Prior to the Formation of t-C4H9(1+) Other Fragment Ions

Based on the surprising observation of an intense C4H9(1+) (m/z 57) peak in the electron impact mass spectrum, the fragmentation of 1,1,2,2,3,3-hexamethylindan (2) was studied by mass-analysed ion kinetic energy spectrometry of its deuterium-labelled analogues.While methyl loss from ions (1+). occurs with high selectivity (92percent) from the positions 1 and 3 without any rearrangement, ions (1+) undergo complete equilibration of the five methyl groups as intact entities.Subsequent multi-step skeletal rearrangement of the (1+) ions leads to formation of tert-butyl ions and to the loss of isobutene and propene, again without concomitant hydrogen exchange.Several kinetic isotope effects and also probably a thermodynamic isotope effect associated with each of these fragmentation processes have been found and their origin is discussed.The possibility of the formation of ion-neutral complexes and is considered on the basis of the labelling and reactivity pattern.

Photoaddition of Alkenes to N-Methyl-1,8-naphthalimide in Methanol. Evidence for the Mechanism of the Formation of the Tetracyclic Adducts.

Irradiation of N-methyl-1,8-naphthalimide (NMN) in the presence of α-methylstyrene (α-MS) or 1,1-diphenylethylene in methanol gives novel tetracyclic imides.The mechanism proposed involves photostimulated electron transfer from the alkene to 1,8-NMN and radical coupling addition of methanol to the resultant radical cation-radical anion pair at the 4-position of the aromatic ring to give an unisolable intermediate with an α,β-unsaturated carbonyl moiety.Absorption of a second photon by this chromophore gives rise to the final product.The predicted regiochemistry and stereochemistry of the reaction were established by using pentadeuterio-α-methylstyrene (16), thus providing strong evidence for the mechanism.