72260-61-8

Basic information

• Product Name: {OCr(C₄₄H₂₈N₄)Cl}
• Synonyms: {OCr(C₄₄H₂₈N₄)Cl}
• CAS NO: 72260-61-8
• Molecular Weight: 716.182
• Mol File: 72260-61-8.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: {OCr(C₄₄H₂₈N₄)Cl}(CAS DataBase Reference)
• NIST Chemistry Reference: {OCr(C₄₄H₂₈N₄)Cl}(72260-61-8)
• EPA Substance Registry System: {OCr(C₄₄H₂₈N₄)Cl}(72260-61-8)

Safety Data

• Hazardous Substances Data: 72260-61-8(Hazardous Substances Data)

Upstream product

• 28110-70-5 chloro(5,10,15,20-tetraphenylporphyrinato)chromium(III) 
• 536-80-1 iodosylbenzene 
• 78833-34-8 (5,10,15,20-tetraphenylporphyrinato)oxochromium(IV) 

Downstream Products

• 108111-11-1 oxo(5,10,15,20-tetraphenylporphyrinato) t-butylamine chromium(IV) 
• 78833-34-8 (5,10,15,20-tetraphenylporphyrinato)oxochromium(IV) 

Relevant articles and documents

Oxidation of Chromium(III) Porphyrins to their ?-Radical Cations or to Oxochromium (IV) Porphyrins

One-electron oxidation of several chromium(III) porphyrins has been studied by steady-state and pulse radiolysis techniques under different conditions.Two types of products are observed: those exhibiting intense broad absorptions at λ >/= 600 nm, ascribed

E.S.R. Evidence for Chromium(V) Porphyrinates

The oxidation of chloro-5,10,15,20-tetraphenylporphyrinatochromium(III) with iodosylbenzene proceeds with oxygen transfer to chromium and two-electron oxidation of the metal to give a chromium(V) porphyrinate complex; the e.s.r. spectra of this complex, its 17O-derivative, and its t-butylamine adduct show strong electron hyperfine interactions with the metal nucleus and the metal ligands and indicate a metal-centred radical as expected for chromium(V).