725-00-8Relevant articles and documents
Effect of CHAPS and CPC micelles on Ir(III) catalyzed Ce(IV) oxidation of aliphatic alcohols at room temperature and pressure
Ghosh, Aniruddha,Saha, Rumpa,Saha, Bidyut
, p. 223 - 237 (2014/05/06)
Kinetics of cerium(IV) oxidation of aliphatic alcohols: ethanol, propanol, propan-2-ol, 1-butanol and 2-butanol were studied at 30 °C in the presence and absence of surfactants in acidic medium. The reaction was studied under pseudo-first-order conditions
Revisiting the reaction of hydroxyl radicals with vicinal diols in water
Jiang, Dong,Barata-Vallejo, Sebastian,Golding, Bernard T.,Ferreri, Carla,Chatgilialoglu, Chryssostomos
supporting information; experimental part, p. 1102 - 1107 (2012/04/04)
The carbonyl products of the reactions of hydroxyl radicals with three vicinal diols (ethane-1,2-diol, propane-1,2-diol and butane-2,3-diol) have been identified and quantified. Hydroxyl radicals were produced by γ-radiolysis of N2O-saturated aqueous solutions. The reactions result in the formation of alkoxyl radicals (~15%) followed by β-fragmentation, and α-hydroxyl alkyl radicals that undergo H2O elimination. The latter process is part of a radical chain reaction at higher diol concentrations.
A novel synthetic method for the preparation of aliphatic aldehydes from the corresponding carboxylic acids
Guo, Yuan,Lu, Zhenhuan,Yao, Libo,Shi, Zhen
experimental part, p. 489 - 492 (2012/01/05)
A novel synthetic method for the preparation of aliphatic aldehydes from the corresponding carboxylic acids via 1,3-dimethylbenzimidazolium salts is provided. 1,3-Dimethylbenzimidazolium salts were rapidly reduced with sodium/ethanol and then hydrolyzed with hydrochloric acid to obtain aliphatic aldehydes, in which the 1,3-dimethylbenzimidazolium salts can be readily achieved from the corresponding carboxylic acids. The mechanism for the reductive reaction of 1,3-dimethylbenzimidazolium salts with sodium/ethanol was discussed.