726-61-4Relevant articles and documents
Synthesis and solid-state NMR studies of P-vinylbenzylphosphonic acid
Frantz, Richard,Durand, Jean-Olivier,Carre, Francis,Lanneau, Gerard F.,Le Bideau, Jean,Alonso, Bruno,Massiot, Dominique
, p. 770 - 775 (2003)
P-Vinylbenzylphosphonic acid (2) was synthesized and crystallized in two phases A and B. The latter phase was easily converted into the former. Both phases were investigated by IR and solid-state 31P and 1H NMR spectroscopy, and X-ra
Preparation and Photophysical Properties of All-trans Acceptor-π-Donor (Acceptor) Compounds Possessing Obvious Solvatochromic Effects
Pan, Yu-Lu,Cai, Zhi-Bin,Bai, Li,Li, Sheng-Li,Tian, Yu-Peng
, p. 1048 - 1056 (2017/09/02)
A series of all-trans acceptor-π-donor (acceptor) compounds (BAQ, SFQ, BLQ, and XJQ) were conveniently synthesised and characterised by infrared, nuclear magnetic resonance, mass spectrometry, and elemental analysis. Their photophysical properties, including linear absorption, one-photon excited fluorescence, two-photon absorption, and two-photon excited fluorescence, were systematically investigated. All the compounds show obvious solvatochromic effects, such as significant bathochromic shifts of the emission spectra and larger Stokes shifts in more polar solvents. Under excitation from a femtosecond Ti:sapphire laser with a pulse width of 140 fs, they all exhibit strong two-photon excited fluorescence, and the two-photon absorption cross-sections in THF are 851 (BAQ), 216 (SFQ), 561 (BLQ), and 447 (XJQ) GM respectively. A combination of density functional theory (DFT) and time-dependent density functional theory (TDDFT) approaches was used to investigate the relationships between the structures and the photophysical properties of these compounds. The results show that they may have a potential application as polarity-sensitive two-photon fluorescent probes.
A new series of two-photon blue/violet fluorescent trans-alkenes: Green synthesis and optical properties
Huang, Jiu-Qiang,Cai, Zhi-Bin,Jin, Fan,Li, Sheng-Li,Tian, Yu-Peng
, p. 164 - 170 (2015/11/16)
A new series of trans-alkenes (3a-3e) containing different electron-donating groups were synthesized by the solvent-free Horner-Wadsworth-Emmons reaction, and characterized by infrared, hydrogen nuclear magnetic resonance, mass spectrometry and elemental analysis. Their UV-visible absorption, one-photon excited fluorescence, two-photon absorption, and two-photon excited fluorescence were systematically investigated in different solvents. Experimental results show different trends in linear and nonlinear optical properties with different donor units. 3a with triphenylamine donor exhibits the best optical properties. It emits strong blue up-converted fluorescence, and the two-photon absorption cross-section can be as large as 218 GM in DCM.