72844-86-1

Basic information

• Product Name: (E)-N-(2-(2-cyanovinyl)phenyl)acetamide
• Synonyms: (E)-N-(2-(2-cyanovinyl)phenyl)acetamide
• CAS NO: 72844-86-1
• Molecular Weight: 186.213
• Mol File: 72844-86-1.mol
• Article Data: 5

Chemical Properties

• CAS DataBase Reference: (E)-N-(2-(2-cyanovinyl)phenyl)acetamide(CAS DataBase Reference)
• NIST Chemistry Reference: (E)-N-(2-(2-cyanovinyl)phenyl)acetamide(72844-86-1)
• EPA Substance Registry System: (E)-N-(2-(2-cyanovinyl)phenyl)acetamide(72844-86-1)

Safety Data

• Hazardous Substances Data: 72844-86-1(Hazardous Substances Data)

Upstream product

• 19591-17-4 o-iodoacetanilide 
• 107-13-1 acrylonitrile 
• 51991-49-2 1-cyano-2-(2'-nitrophenyl)ethene 
• 2001-33-4 o-nitrocinnamamide 
• 103-84-4 Acetanilid 
• 614-76-6 N-acetyl-2-bromoaniline 
• 58106-57-3 (E)-3-(2-aminobenzene)acrylonitrile 
• 108-24-7 acetic anhydride 

Downstream Products

• 72248-92-1 2-methylquinoline-3-carbonitrile 
• 72844-90-7 o-(2-trans-Cyanoethenyl)thioacetanilide 
• 580-22-3 2-aminoquinoline 

Relevant articles and documents

Heterogeneous C-H alkenylations in continuous-flow: Oxidative palladium-catalysis in a biomass-derived reaction medium

Herein we report the unprecedented Fujiwara-Moritani reaction catalysed by the commercially available heterogeneous palladium catalyst Pd/C. The reaction works efficiently in GVL, a biomass derived solvent, in the coupling between variously substituted ac

A straightforward synthesis of benzothiazines

(Chemical Equation Presented) A series of 4H-3,1-benzothiazines have been successfully synthesized through a three-step sequence starting from commercially available 2-iodoaniline. The key step consists of the cyclization of compounds 6 via an intramolecu

Photochemical Synthesis. Conversion of o-Vinylthioanilides to Quinolines

Quinoline derivatives are formed in fair to good yields when acetonitrile solutions of o-vinylthioanilides are irradiated with Pyrex-filtered light.The transformation is a singlet reaction and involves intramolecular cycloaddition of the thioamide, yielding unstable thietanes, as the initial step.In the case of o-(1-trans-propenyl)thioacetanilide (2a) the corresponding thietane has been detected by 1H NMR spectroscopy by irradiating a toluene solution of the compound at -78 deg C.The quantum yield of quinoline formation from 2a appeared to be solvent dependent.Concomitant with quinoline formation, triplet cis-trans isomerization of the vinyl moiety takes place.In the case of 2a the quantum yield for trans -> cis isomerization is 0.506.A variable-temperature 1H NMR study of 2,3-dimethylquinoline in toluene solution has also been performed.For the 2,3-dimethylquinoline-toluene complex the enthalpy and entropy of formation are -1.03 +/- 0.10 kcal/mol and -3.7 +/- 0.2 gibbs/mol, respectively.