72850-81-8

Basic information

• Product Name: Ethyl 2-phenoxy-4-(trifluoromethyl)-5-thiazolecarboxylate
• Synonyms: Ethyl 2-phenoxy-4-(trifluoromethyl)-5-thiazolecarboxylate
• CAS NO: 72850-81-8
• Molecular Weight: 317.289
• Mol File: 72850-81-8.mol
• Article Data: 4

Chemical Properties

• CAS DataBase Reference: Ethyl 2-phenoxy-4-(trifluoromethyl)-5-thiazolecarboxylate(CAS DataBase Reference)
• NIST Chemistry Reference: Ethyl 2-phenoxy-4-(trifluoromethyl)-5-thiazolecarboxylate(72850-81-8)
• EPA Substance Registry System: Ethyl 2-phenoxy-4-(trifluoromethyl)-5-thiazolecarboxylate(72850-81-8)

Safety Data

• Hazardous Substances Data: 72850-81-8(Hazardous Substances Data)

Upstream product

• 584-08-7 potassium carbonate 
• 108-95-2 phenol 
• 72850-52-3 ethyl 2-chloro-4-(trifluoromethyl)thiazole-5-carboxylate 
• 72850-53-4 ethyl 2,3-dihydro-2-oxo-4-trifluoromethyl-5-thiazole-carboxylate 
• 372-29-2 ethyl 3-amino-4,4,4-trifluoro-2-butenoate 

Relevant articles and documents

Syntheses and Reactions of 2-Halo-5-thiazolecarboxylates

A variety of 2-halo-5-thiazolecarboxylates was prepared from substituted-3-aminoacrylates and 3-ketoesters.Selective reduction of 2-chloro-5-thiazolecarboxylates 4a, 4i and 4j with sodium borohydride in ethanol provided the corresponding 2-halo-5-thiazolemethanols 27 - 29.Nucleophilic displacement on methyl methanesulfonate (32c) occured selectivity at the 5-substituent to provide 2-chloro-4-(trifluoromethyl)-5-(heteroatom-substituted methyl)thiazoles 32d-f.

2,4-Disubstituted-5-thiazole-carboxylic acids and derivatives

2,4-Disubstituted-5-thiazolecarboxylic acids and derivatives thereof have been found to reduce herbicidal injury of corn, rice and sorghum plants due to the application thereto of acetamide herbicides.