732-92-3Relevant articles and documents
Crystal structure of 5-chlorosalicylic aldehyde isonicotinoyl hydrazone
Chumakov,Antosyak,Tsapkov,Samus
, p. 335 - 339 (2001)
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Synthesis and characterization of a series of isoniazid hydrazones. Spectroscopic and theoretical study
Ferraresi-Curotto, Verónica,Echeverría, Gustavo A.,Piro, Oscar E.,Pis-Diez, Reinaldo,González-Baró, Ana C.
, p. 436 - 447 (2016/12/27)
A family of hydrazones of isoniazid and a group of hydroxybenzalaldehydes (vanillin, 5-bromovanillin, 5-chlorosalicylaldehyde and 5-bromosalicylaldehyde) were obtained and fully characterized. The results, including theoretical data, are comparatively ana
Heteroleptic binuclear copper(I) complexes bearing bis(salicylidene)hydrazone ligands: Synthesis, crystal structure and application in catalytic N-alkylation of amines
Prakash, Govindan,Nirmala, Muthukumaran,Ramachandran, Rangasamy,Viswanathamurthi, Periasamy,Malecki, Jan Grzegorz,Sanmartin, Jesus
, p. 62 - 69 (2015/02/19)
A new series of heteroleptic binuclear Cu(I) bis(salicylidene)hydrazone complexes (1-4) bearing triphenylphospine coligands have been synthesized from the reactions of copper(II) precursor complex [CuCl2(PPh3)2] with oxadiazole compounds A-D, respectively. It has been observed that the oxadiazole compounds undergo ring cleavage with in situ reduction of Cu(II) ion, during the formation of complexes (1-4). The oxadiazoles (A-D) and the Cu(I) complexes (1-4) have been characterized by analytical and spectroscopic methods. Single crystal X-ray diffraction study of complex 2 has revealed a distorted tetrahedral geometry around each Cu(I) center. Catalytic efficiency of the new complexes on the N-alkylation of amines using alcohols was studied under optimized conditions. The new complexes have also been tested for their catalytic activity towards the direct N-alkylation of 2-nitropyridine.