7337-45-3 Usage
Description
BORANE-TERT-BUTYLAMINE COMPLEX is a chemical compound that consists of a borane molecule bonded to a tert-butylamine molecule. It is known for its strong reducing properties and ability to form stable adducts with various substrates.
Uses
Used in Non-Destructive Analyses and Conservation Treatments:
BORANE-TERT-BUTYLAMINE COMPLEX is used as a reactant in non-destructive analyses and conservation treatments of Indian drawings, providing a means to study and preserve these valuable artifacts without causing damage.
Used in Dehydrogenation Reactions:
In the chemical industry, BORANE-TERT-BUTYLAMINE COMPLEX serves as a reactant in dehydrogenation reactions mediated by ruthenium bidentate phosphine complexes or ruthenium/iridium bis(N-heterocyclic carbene) complexes, facilitating the conversion of alcohols to aldehydes or ketones.
Used in the Formation of σ-Borane Complexes:
BORANE-TERT-BUTYLAMINE COMPLEX is utilized in the formation of σ-borane complexes, which are important intermediates in various organic synthesis processes.
Used in Ethanolysis of Amine-Borane Adducts:
This complex is used in the ethanolysis of amine-borane adducts to form a reducing system for transfer hydrogenation of terminal olefins, which is a key step in the synthesis of certain organic compounds.
Used in Photochemical Hydroboration and Oxidation:
BORANE-TERT-BUTYLAMINE COMPLEX is employed in photochemical hydroboration and oxidation processes, particularly for the modification of single-walled carbon nanotubes, enhancing their properties for various applications.
Used in Stereoselective Reduction:
In the field of organic chemistry, BORANE-TERT-BUTYLAMINE COMPLEX is used as a strong co-reducing agent in the stereoselective reduction of a steroidal ketone, allowing for the selective formation of specific stereoisomers.
Used in the Synthesis of Copper (I) Oxide Nanoparticles:
BORANE-TERT-BUTYLAMINE COMPLEX is utilized as a co-reducing agent in the syntheses of copper (I) oxide nanoparticles, which have potential applications in catalysis, sensors, and electronics.
Used in the Synthesis of Diphosphine-Protected Gold Nanoclusters:
This complex is used as a reducing agent in the synthesis of diphosphine-protected gold nanoclusters, which have potential applications in catalysis and materials science.
Used in the Synthesis of 4-Acetoxycinnamyl Alcohols:
BORANE-TERT-BUTYLAMINE COMPLEX is employed as a reducing agent in the synthesis of 4-acetoxycinnamyl alcohols, which are important intermediates in the production of pharmaceuticals and other organic compounds.
Check Digit Verification of cas no
The CAS Registry Mumber 7337-45-3 includes 7 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 4 digits, 7,3,3 and 7 respectively; the second part has 2 digits, 4 and 5 respectively.
Calculate Digit Verification of CAS Registry Number 7337-45:
(6*7)+(5*3)+(4*3)+(3*7)+(2*4)+(1*5)=103
103 % 10 = 3
So 7337-45-3 is a valid CAS Registry Number.
InChI:InChI=1/C4H11N.BH3/c1-4(2,3)5;/h5H2,1-3H3;1H3
7337-45-3Relevant articles and documents
Efficient reductions of dimethylhydrazones using preformed primary amine boranes
Frabitore, Christian,Lépeule, Jérome,Livinghouse, Tom,Robinson, William C.,Towey, Bradley
supporting information, (2021/12/21)
A convenient method for the reduction of N,N-dimethylhydrazones using amine borane complexes generated in situ is described. It was found that primary amine borane complexes performed exceedingly well at reducing N,N-dimethylhydrazones in as little as 1.1 equivalents, furnishing the corresponding air-sensitive hydrazine products in excellent yields.
Activation of sodium borohydride via carbonyl reduction for the synthesis of amine- And phosphine-boranes
Hamann, Henry J.,Lin, Randy,Veeraraghavan Ramachandran, P.
supporting information, p. 16770 - 16774 (2021/12/08)
A highly versatile synthesis of amine-boranes via carbonyl reduction by sodium borohydride is described. Unlike the prior bicarbonate-mediated protocol, which proceeds via a salt metathesis reaction, the carbon dioxide-mediated synthesis proceeds via reduction to a monoformatoborohydride intermediate. This has been verified by spectroscopic analysis, and by using aldehydes and ketones as the carbonyl source for the activation of sodium borohydride. This process has been used to produce borane complexes with 1°-, 2°-, and 3°-amines, including those with borane reactive functionalities, heteroarylamines, and a series of phosphines.
Method for the production of amine borane complex (by machine translation)
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Paragraph 0037; 0038, (2017/12/05)
The invention belongs to the technical field of material preparation, in particular relates to a method for the production of amine borane complex. This invention adopts the borane amine of the direct reaction of an inert gas stream, by regulating the ratio of the two, the need for further post-processing, to make the final product amine complex and offer. In the reaction process such impurity is introduced into the salt-free, does not use an organic solvent; the use of borohydride such as the reagent to produce the borane, for now the current system, can avoid direct operation of toxic gas borane. The method of the invention is simple in operation, the product has high purity, low cost, and can be continuous large-scale production. At the same time, the method and other way to produce the amine borane complex equipment compatible, production equipment by simple method can be used to adjust the production. (by machine translation)
