73724-92-2Relevant articles and documents
HETEROCYCLIC ANALOGS OF PLEIADIENE. 63. SYNTHESIS AND CRYSTAL STRUCTURE OF 1-AMINOPERIMIDINES
Pozharskii, A. F.,Kryshtalyuk, O. V.,Aleksandrov, G. G.,Kuz'menko, V. V.
, p. 92 - 98 (2007/10/03)
By action of O-picrylhydroxylamine on perimidine and 2-methylperimidine, we have synthesized their 1-amino derivatives.An x-ray diffraction investigated of 1-aminoperimidine showed that the amino group in them is found in a pyramidal configuration with the axis of the unshared electron pair lying in the plane of the heterocyclic ring, oriented toward the μ-carbon atom.